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The correct relationship between the pH ...

The correct relationship between the `pH` of isomolar solutions of sodium oxide `(pH_(1))`, sodium sulphide `(pH_(2))`, sodium selenide `(pH_(3))` and sodium telluride `(pH_(4))` is

A

`pH_(1) gt pH_(2)~~pH_(3) gtPH_(4)`

B

`pH_(1) lt pH_(2) lt pH_(3) lt PH_(4)`

C

`pH_(1) lt pH_(2) lt pH_(3) ~~PH_(4)`

D

`pH_(1) gtpH_(2) gt pH_(3) gt PH_(3)`

Text Solution

Verified by Experts

The correct Answer is:
D

Acidic character increases in the order
`H_(2)O lt H_(2)S lt H_(2)Se lt H_(2)Te`
Basic character of conjugate bases will be in the order
`O^(2-)gt S^(2-) gt Se^(2-) gt Te^(2-)`
More the basic character, more the pH
`:.` pHs are in the order
`pH_(1)gt pH_(2)gt pH _(3) gt pH _(4)`
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