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The pH of the solutions produced by mixi...

The pH of the solutions produced by mixing equal volumes of `2.0 xx 10^(-3) M HClO_(4)` and `1.0 xx 10^(-2) MKClO_(4)` is

A

2.7

B

2.3

C

`3.0`

D

`1.0`

Text Solution

Verified by Experts

The correct Answer is:
C

`H^(+)` ions obtained only from `HClO_(4)` which ionises completely ( being a strong acid ). Equal volume of `KClO_(4)` solution added reduces `(H^(+))` ions to half `3.0`
`:. |H^(+)|=(2xx10^(-3))/(2)`
Hence `pH =-log (10^(-3))=3.0`
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