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A buffer solution is prepared in which t...

A buffer solution is prepared in which the concentration of `NH_(3)` is `0.30 M` and the concentration of `NH_(4)^(+)` is `0.20 M`. If the equilibrium constant, `K_(b)` for `NH_(3)` equals `1.8xx10^(-5)`, what is the `pH` of this solution? (`log 2.7=0.43`)

A

9.08

B

9.43

C

11.72

D

8.73

Text Solution

Verified by Experts

The correct Answer is:
B

`pOH=pK_(b)+log.(|NH_(3)^(+)|)/(|NH_(3)|)`
`=-log (1.8 xx 10^(-5))+log. (0.2)/(0.3)`
`=4.74 +log .(0.2)/(0.2)=4.56`
`pH ==14-4.56=9.44`
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DINESH PUBLICATION-IONIC EQUILIBRIUM -REVISION QUESTIONS FROM COMPETITVE EXAMS
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