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Among the species CO2, CO3^(2-), CH3COO^...

Among the species `CO_2, CO_3^(2-), CH_3COO^(-)`, CO, HCHO which has longest carbon-oxygen bond

A

`CO_2`

B

`CH_3COO^-`

C

CO

D

`CO_3^(2-)`

Text Solution

Verified by Experts

The correct Answer is:
D

CO, is a resonance hybrid of following three structures :
CO is Mainly a resonance hybrid of following two structures :
`: overset(-)(C)-=O :^(+)harr : C=overset(ddot)(O : )`

`H-oversetoverset(H)(|)C=O` does not show resonance.
With more single bond character in resonance hybrid of `CO_3^(2-), C-O` bond length is longest.
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DINESH PUBLICATION-CHEMICAL BONDING AND MOLECULAR STRUCTURE-REVISION
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  2. The maximum number of 90^(@) angles between bond pair-bond pair of ele...

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  3. Among the species CO2, CO3^(2-), CH3COO^(-), CO, HCHO which has longes...

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  4. The boiling point of methanol is greater than methyl thiol because

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  5. Two nodal planes are present in

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  6. In acetylene molecule, the carbon atoms are linked by:

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  7. Shape of O2F2 is similar to that of

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  8. The ONO bond angle is maximum in

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  9. The dipole moment is the highest for

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  10. The decreasing order of bond angle is

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  11. H2O is dipolar, whereas BeF2 is not. It is because

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  12. In an octahedral structure , the pair of d orbitals involved in d^(2)...

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  14. Among the following the pair in which the two species are not isostruc...

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  15. Decreasing order of C-C bond length is (I) C2H4 (II) C2H2 (III) C6 H6 ...

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  16. How many sigma and pi bonds are present in toluene ?

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  17. If the molecule of HCl were totally polar, the expected value of dipol...

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  18. Which one of the following molecules has the smallest bond angle ?

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  19. Which one of the following sepcies is diamagnetic in nature ?

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  20. Lattice energy of an ionic compound depedns upon :

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