Home
Class 12
CHEMISTRY
Assuming that Hund's rule is violated th...

Assuming that Hund's rule is violated the bond order and magnetic nature of the diatomic molecle `B_(2)` is

A

1 and diamagnetic

B

0 and diamagnetic

C

1 and paramagnetic

D

0 and paramagnetic

Text Solution

Verified by Experts

The correct Answer is:
A

If Hund's rule is violated, molecular electronic configuration of `B_2` will
`sigma_(1s)^2 sigma_(1s)^(**2) sigma_(2s)^2 sigma_(2s)^(2+) pi_(2px)^2 pi_(2py)^0`
Bond order `1/2`[6-4]= 1
It will be diamagnetic due to the presence of unpaired electrons.
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    DINESH PUBLICATION|Exercise Comprehension M.C.Q|24 Videos
  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    DINESH PUBLICATION|Exercise Matrix Match|4 Videos
  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    DINESH PUBLICATION|Exercise Unit Test - 1|20 Videos
  • CARBOXYLIC ACIDS

    DINESH PUBLICATION|Exercise BRAIN STORMING MULTIPLE CHOICE QUESTIONS (MCQS)|13 Videos
  • CHEMICAL KINETICS

    DINESH PUBLICATION|Exercise Additional Numerical Problems For Practice|16 Videos

Similar Questions

Explore conceptually related problems

Assuming that Hund’s rule is violated, the bond order and magnetic nature of the diatomic molecule C_(2) is :

Bond order and magnetic moment of CO^+ is

Bond order and magnetic nature of CN^- are respectively

Find the bond order of B_2

The bond order and magnetic behaviour of O_2^- ion are, respectively :

Valence bond theory explains the geometry and magnetic nature of the coordination compounds .

DINESH PUBLICATION-CHEMICAL BONDING AND MOLECULAR STRUCTURE-REVISION
  1. Which of the following statement is false

    Text Solution

    |

  2. The bond angle formed by different hybrid orbitals are in the order

    Text Solution

    |

  3. Assuming that Hund's rule is violated the bond order and magnetic natu...

    Text Solution

    |

  4. In which of the following molecules is hydrogen bridge bond present ?

    Text Solution

    |

  5. Complete the following reaction

    Text Solution

    |

  6. In which one of the following species , the central atom has the tuype...

    Text Solution

    |

  7. Which of the following conversion involves change in both hybridizatio...

    Text Solution

    |

  8. The correct order of increasing bond angle in the following species is

    Text Solution

    |

  9. Which of the following is a the most preferred and hence of the lower ...

    Text Solution

    |

  10. In which of the following, the central atoms has two lone pairs of ele...

    Text Solution

    |

  11. Which of the two lons from the list given have the geometry that is ex...

    Text Solution

    |

  12. Which of the following is a the most preferred and hence of the lower ...

    Text Solution

    |

  13. The pairs of species of oxygen and their magnetic behaviour are noted ...

    Text Solution

    |

  14. The covalent bond length is the shortest in which of the following bon...

    Text Solution

    |

  15. Among the molecules, SO2, SF4, ClF3. BrF5 and XeF4 which of the follow...

    Text Solution

    |

  16. The hydrogen bond is shortest in

    Text Solution

    |

  17. Which one of the following is not correct with respect to bond length ...

    Text Solution

    |

  18. Which of the following species contains three bond pair and one lone ...

    Text Solution

    |

  19. The percentage of p character of hybrid orbitals in graphite and diamo...

    Text Solution

    |

  20. Which one of the following is the correct statement

    Text Solution

    |