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It is a common observation that many com...

It is a common observation that many compounds containing hydrogen attached to highly electronegative elements such as oxygen, nitrogen, or fluorine, often exhibit unexpected properties, such as relatively high melting points, boiling points, viscosity, solubility in water etc Such an unexpected behaviour can be explained on the basis of hydrogen bonding. When a hydrogen atom is attached to a highly electronegative element of small size such as F. N, 0. etc. the electronegative atoms strongly attracts the shared pair of electrons towards it self. As a result, the hydrogen atom becomes slightly positive and the electronegative element becomes slightly negative when two molecules of such a substance say HF come close to each other, the negatively charged fluorine atom of one molecule attracts the positively charged hydrogen atom of the other molecule. A hydrogen atom, thus links to highly electronegative atoms, one by a strong covalent bond and the other by weak electrostatic attraction as shown ahead `overset(delta+)H-overset(delta-)F....overset(delta+)H-overset(delta-)F`, the dotted line represents a hydrogen bond.
The boiling point of p-nitrophenol is higher than that of o-nitrophenol because

A

`NO_2` group at p-position behaves in a different way from that at o-position

B

intramolecular hydrogen bonding exists in p-nitrophenol

C

there is intermolecular bonding p-nitrophenol

D

p-nitrophenol has a higher molecular mass than o-nitrophenol

Text Solution

Verified by Experts

The correct Answer is:
C
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DINESH PUBLICATION-CHEMICAL BONDING AND MOLECULAR STRUCTURE-Comprehension M.C.Q
  1. It is a common observation that many compounds containing hydrogen att...

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  2. It is a common observation that many compounds containing hydrogen att...

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  3. It is a common observation that many compounds containing hydrogen att...

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  4. It is a common observation that many compounds containing hydrogen att...

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  5. It is a common observation that many compounds containing hydrogen att...

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  6. It is a common observation that many compounds containing hydrogen att...

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  7. Atomic orbitals of bonded atoms combine to form molecular orbitals. Th...

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  8. Atomic orbitals of bonded atoms combine to form molecular orbitals. Th...

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  9. Atomic orbitals of bonded atoms combine to form molecular orbitals. Th...

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  10. Atomic orbitals of bonded atoms combine to form molecular orbitals. Th...

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  11. Atomic orbitals of bonded atoms combine to form molecular orbitals. Th...

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  12. Atomic orbitals of bonded atoms combine to form molecular orbitals. Th...

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  13. Atomic orbitals of bonded atoms combine to form molecular orbitals. Th...

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  14. A polar covalent bond with positive and negative charge centres at its...

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  15. A polar covalent bond with positive and negative charge centres at its...

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  16. A polar covalent bond with positive and negative charge centres at its...

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  17. A polar covalent bond with positive and negative charge centres at its...

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  18. A polar covalent bond with positive and negative charge centres at its...

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  19. A polar covalent bond with positive and negative charge centres at its...

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  20. A polar covalent bond with positive and negative charge centres at its...

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