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The incorrect order of decreasing boilin...

The incorrect order of decreasing boiling point is

A

`HF gt HI gt HBr gt HCl`

B

`H_2O gt H_2Te gt H_2Se gt H_2S`

C

`Br_2 gt Cl_2 gt F_2`

D

`CH_4 gt GeH_4 gt SiH_4`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the incorrect order of decreasing boiling points among the given molecules (HF, HI, HBr, HCl), we need to analyze the boiling points based on the types of intermolecular forces present and the molecular weights of the compounds. ### Step-by-Step Solution: 1. **Identify the Compounds and Their Intermolecular Forces:** - HF (Hydrogen Fluoride): Exhibits strong hydrogen bonding due to the highly electronegative fluorine atom. - HCl (Hydrogen Chloride): Exhibits dipole-dipole interactions and some hydrogen bonding, but weaker than HF. - HBr (Hydrogen Bromide): Similar to HCl but with a larger molecular size, leading to weaker dipole-dipole interactions. - HI (Hydrogen Iodide): Exhibits weaker dipole-dipole interactions compared to HBr and HCl due to larger size and lower electronegativity of iodine. 2. **Analyze the Boiling Points:** - HF has a significantly higher boiling point due to strong hydrogen bonding. - HCl has a lower boiling point than HF but higher than HBr and HI. - HBr has a lower boiling point than HCl but higher than HI. - HI has the lowest boiling point among these due to the weakest intermolecular forces. 3. **Order the Compounds by Boiling Points:** - The expected order of boiling points from highest to lowest is: - HF > HCl > HBr > HI 4. **Identify the Incorrect Order:** - If we consider the options provided, any order that suggests HI has a higher boiling point than HBr, HCl, or HF would be incorrect. - For example, if an option states HI > HBr > HCl > HF, this would be the incorrect order of decreasing boiling points. ### Conclusion: The incorrect order of decreasing boiling point among the options provided is likely to be one that places HI above HBr, HCl, or HF.

To determine the incorrect order of decreasing boiling points among the given molecules (HF, HI, HBr, HCl), we need to analyze the boiling points based on the types of intermolecular forces present and the molecular weights of the compounds. ### Step-by-Step Solution: 1. **Identify the Compounds and Their Intermolecular Forces:** - HF (Hydrogen Fluoride): Exhibits strong hydrogen bonding due to the highly electronegative fluorine atom. - HCl (Hydrogen Chloride): Exhibits dipole-dipole interactions and some hydrogen bonding, but weaker than HF. - HBr (Hydrogen Bromide): Similar to HCl but with a larger molecular size, leading to weaker dipole-dipole interactions. ...
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DINESH PUBLICATION-CHEMICAL BONDING AND MOLECULAR STRUCTURE-Brain Teaser-1
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  2. Which of the following gaseous molecules is polar ?

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  3. The incorrect order of decreasing boiling point is

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  4. Which of the following statements is not regarding bonding molecular o...

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  5. In the formation of N2^+ from N2, the electron is removed from

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  6. The magnitude of lattice energy of a solid increases if

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  7. The electronegativities of F, Cl, Br, and I are 4.0, 3.0, 2.8, and 2.5...

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  8. In which of the following pairs does the first compound not have a hig...

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  9. Which of the following compounds has the least tendency to form hydro...

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  10. In which of the following set of molecules is the order of boiling poi...

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  11. Which of the following statement is correct?

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  12. Which among the following molecules is diamagnetic ?

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  13. The energy of sigma(2s), is greater than that of sigma(1s)^** orbital ...

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  14. A wedding ring presented to a bride contains 788 mg of gold and the re...

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  15. The bond that stabilizes the secondary structure of proteins is

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  16. Which of the following does not contain a coordinate bond?

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  17. Hybridisation of central atom in IC l2^+ is

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  18. The transition of an electron from a 4s orbital to ls orbital in hydro...

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  19. The chemical species having same number of electrons in the outermost...

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  20. From among the following triatomic species the least angle around the ...

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