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Reaction of benzonitrile with methyl mag...

Reaction of benzonitrile with methyl magnesium iodide followed by hydrolysis gives :

A

toluene

B

acetophenone

C

Benzoic acid

D

iodobenzene

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To solve the problem of the reaction of benzonitrile with methyl magnesium iodide followed by hydrolysis, we can break down the steps as follows: ### Step 1: Identify the Reactants - **Benzonitrile**: This is an aromatic compound with the formula C6H5CN, which consists of a benzene ring attached to a nitrile group (C≡N). - **Methyl Magnesium Iodide (CH3MgI)**: This is a Grignard reagent, which is a strong nucleophile. ### Step 2: Reaction of Benzonitrile with Methyl Magnesium Iodide - When benzonitrile reacts with methyl magnesium iodide, the nucleophilic methyl group (CH3-) from the Grignard reagent attacks the electrophilic carbon of the nitrile group (C≡N). - This results in the formation of an intermediate compound, which is a ketimine. ### Step 3: Hydrolysis of the Intermediate - The intermediate ketimine formed from the reaction is then subjected to hydrolysis. Hydrolysis involves the addition of water (H2O) in the presence of an acid (often H3O+). - During hydrolysis, the ketimine is converted into a ketone. ### Step 4: Identify the Final Product - The final product after hydrolysis is **Acetophenone**, which has the structure C6H5C(O)CH3. It is a ketone with a phenyl group (C6H5) and an acetyl group (C(O)CH3). ### Conclusion - Therefore, the reaction of benzonitrile with methyl magnesium iodide followed by hydrolysis gives **Acetophenone**. ### Final Answer The product formed is **Acetophenone (C6H5C(O)CH3)**. ---

To solve the problem of the reaction of benzonitrile with methyl magnesium iodide followed by hydrolysis, we can break down the steps as follows: ### Step 1: Identify the Reactants - **Benzonitrile**: This is an aromatic compound with the formula C6H5CN, which consists of a benzene ring attached to a nitrile group (C≡N). - **Methyl Magnesium Iodide (CH3MgI)**: This is a Grignard reagent, which is a strong nucleophile. ### Step 2: Reaction of Benzonitrile with Methyl Magnesium Iodide - When benzonitrile reacts with methyl magnesium iodide, the nucleophilic methyl group (CH3-) from the Grignard reagent attacks the electrophilic carbon of the nitrile group (C≡N). ...
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DINESH PUBLICATION-CYANIDES, ISOCYANIDES, NITROCOMPOUNDS AND AMINES-Unit test - 8
  1. Reaction of benzonitrile with methyl magnesium iodide followed by hydr...

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  2. Select incorrect statement

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  3. H(2)O is reduce with Sn//HCl. Product formed

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  4. RNH(2) can be converted into R, NH and no other amine by

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  5. Which is general order of basicity for water and amines

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  6. Consider following hydrogen-bonded amines I and II Select the cor...

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  7. Which is the strongest conjugate acid ?

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  8. When (CH(3))(3)CNH(3)^(+)Cl^(-) is heated, product is

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  9. Select correct statement (s), about the following reaction [(CH(3))(3)...

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  10. Major alkene of the following reaction is {:(CH(3)-C CH(2)CH(3)),(" ...

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  11. Exhaustive methylation of CH(3)CH(2)NH(2) forms

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  12. Following 2^(@) amine has chiral carbon as indicated H-underset(CH(3))...

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  13. Major product of the following reaction is {:(" "NH(...

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  14. Consider the following reaction underset((A))(CH(3)CONH(2)) overset(...

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  15. Which is soluble in NONO(2) and dil HCl mixture forming salt ?

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  16. Tertiary amine is oxidized to oxide by

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  17. Cope elimination is an intramolecular, E(2) reaction because

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  18. Cope elimination

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  19. In gas phase, the basicities of amines increase in the order NH(3) lt ...

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  20. In aqueous phase basicity of amines is in order NH(3) lt (CH(3))(3)N...

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  21. Which of the following chemicals are used to manufacture methyl isocya...

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