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Which of the following reaction will not...

Which of the following reaction will not give primary amine ?

A

`CH_(3)CONH_(2) overset(KOH, Br_(2))(rarr)`

B

`CH_(3)CN overset(LiAlH_(4))(rarr)`

C

`CH_(3)NC overset(LiAlH_(4))(rarr)`

D

`CH_(3)CONH_(2) overset(LiAlH_(4))(rarr)`

Text Solution

Verified by Experts

The correct Answer is:
C
Methyl isocyanide would produce secondary amine.
`CH_(3)NC overset(LiAlH_(4))(rarr) CH_(3)NHCH_(3)`
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DINESH PUBLICATION-CYANIDES, ISOCYANIDES, NITROCOMPOUNDS AND AMINES-REVISION QUESTION
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  2. In the following reaction, X is X overset("Bromination")(rarr) Y und...

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  3. Which of the following reaction will not give primary amine ?

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  4. How many isomeric forms of C(7)H(9)N contain a benzene ring ?

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  5. In amines, the hybridisation state of N is

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  6. In the reduction of nitrobenzene, which of the following is the interm...

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  7. On reaction with HNO(2)C(2)H(5)NH(2) produces .

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  8. Reaction of aniline with acety1 chloride in the presence of NaOH gives...

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  9. C(3)H(9)N cannot represent

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  10. Compound A on reduction gives B which on further reaction with CHCl(3)...

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  11. Which of the following compounds cannot be identified by carbyl amine ...

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  12. In the sequence given above Z is

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  13. In the above reaction, X stands for

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  14. What is Hinsberg reagent?

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  15. Reduction of H(3)C-NC with hydrogen in the presence of Ni//Pt catalyst...

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  16. The electrophile involved in the nitration of benzene is

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  17. Unpleasant smell of carbylamine is obtained when chloroform and alcoho...

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  18. A compound that will form an offensive smell when heated ith chlorofor...

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  19. Action of HNO(2) on ethylamine gives

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  20. Which of the following is most basic in nature ?

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