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When nitrobenzene is treated with Br(2)...

When nitrobenzene is treated with `Br_(2)` in presence of `FeBr_(3)`, the major product formed is `m-`bromo`-`nitrobenzene. Statement which is related to obtain the `m-`isomer is

A

the intermediate carbocation formed after initial attack of `Br^(+)` at the meta-position is least stabilised

B

the electron density on meta carbon is more than that on ortho and para-positions

C

loss of aromaticity when `Br^(+)` attacks at the ortho and para positions and not at meta position

D

None of these.

Text Solution

Verified by Experts

The correct Answer is:
B

In the presence of `FeBr_(3)`, it is an electrophilic substitution reaction. As the product of bromination is meta, it means electron density is more at meta - position than at `o-` and `p-`. The product is m-bromo-nitrobenzene.
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