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Write the expressioin for the equilibriu...

Write the expressioin for the equilibrium constant for each of the following reactions?
(i) `2NOCl(g) ltimplies 2NO(g) + Cl_(2)(g)`
(ii) `C(s) +CO_(2) (g) hArr 2CO(g)`
(iii) `I_(2) (s) + 5F_(2) (g) hArr 2IF_(5) (g)`
(iv) `FeO(s) +CO(g) hArr Fe (s) +CO_(2)(g)`
(v) `Na_(2) CO_(3) (s) + SO_(2) (g) +1//2O_(2) (g) hArr Na_(2)SO_(4)(s) + CO_(2) (g).`

Text Solution

Verified by Experts

`(i) 2NOCI (g) hArr 2NO(g) +CI_(2)(g)`
`K_(c) =[[NO(g)]^(2)[CI_(2)(g)]]/[[NOCI(g)]^(2)] " and " K_(p) =((pNO)^(2)(pCI_(2)))/((pNOCI)^(2))`
`(ii) K_(c) =[[CO(g)]^(2)]/[[CO_(2)(g)]] " and " K_(p) =((pCO)^(2))/((pCO_(2)))`
`(iii) K_(c) =[[IF_(5)(g)]^(2)]/[[F_(2)(g)]^(5)]" and " K_(p) = ((pIF_(5))^(2))/((pF_(2))^(5))`
`(iv) K_(c) = [[CO_(2)(g)]]/[[CO(g)]] " and " K_(p) = ((pCO_(2)))/((pCO))`
`(v) K_(c) = [[CO_(2) (g) ]]/[[SO_(2)(g)][O_(2)(g)]^(1//2))" and " K_(p) =((pCO_(2)))/((pSO_(2))(pO_(2))^(1//2))`
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