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BCl(3) exists as monomer whereas AlCl(3)...

`BCl_(3)` exists as monomer whereas `AlCl_(3)` is dimerised through halogen bridging. Give reason, Explain the structre of the dimer of `AlCl_(3)` also.

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### Step-by-Step Solution: 1. **Understanding the Molecular Structure of BCl₃**: - Boron trichloride (BCl₃) is a molecule where boron is bonded to three chlorine atoms. - Boron has three valence electrons and forms three covalent bonds with chlorine, resulting in a trigonal planar geometry. - Importantly, boron does not have any vacant d-orbitals in its valence shell (2s² 2p¹), which limits its coordination number to 3. Therefore, BCl₃ exists as a stable monomer. 2. **Understanding the Molecular Structure of AlCl₃**: ...
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Anhydrrous AlCl_(3) is

AlCl_(3) exist as dimer while BCl_(3) exist as monomer, why?

Anhydrous AlCl_(3) is obtained when :

BCl_(3) is trigonal planr while AlCl_(3) is tetrahedral in dimeric state. Explain.

DINESH PUBLICATION-P BLOCK ELEMENTS (GROUP 13 AND 14 )-Short answer type
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  6. When BCl(3) is treated with water, it hydrolyses and forms [B(OH)(4)]^...

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  8. Explain the following : (a) Boron has high melting and boiling point...

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  9. Identify the compound A, X and Z in the following reactions: (i) A+2...

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  10. Complete the following chemical equations: (i) z+3LiAlH(4)rarrX+3Li...

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  11. Describe the general trends in the following properties of the element...

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  12. Account for the following observation: (i) AlCl(3) is Lewis acid (...

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  13. When aqueous solution of borax is acidified with hydrochloric acid, a ...

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  14. Three pairs of compounds are given below, identify that compound in e...

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  15. BCl(3) exists as monomer whereas AlCl(3) is dimerised through halogen ...

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  16. Explain why BF(3) exist but BH(3) does not.

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  17. What are silicones ?

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  18. A compound (A) of boron reacts with Nme(3) to give an adduct (B) which...

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  19. A non-metallic element of group 13, used in making bullet prrof vests ...

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  20. A tetravalent element forms monoxide and dioxide with oxygen. When air...

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