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A non-metallic element of group 13, used...

A non-metallic element of group 13, used in making bullet prrof vests is extremely hard solid of black colour. It can exist in many allotroic forms and has unusally high melting point. Its trifluoride acts as Lewis acid towards ammonia. The element exhibits maximum covalency of four. Identify the element and write the reaction of tits triffuoride with ammonia. Explain why does the trifuoride act as Lewis acid.

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Verified by Experts

The available information suggests that the element is boron, Boron trifulouride reacts with ammonia to form an addition product.

for the lewis acid character of `BF_3` consult section 11.2
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Boron, the first member of group 13 (p-block) is a typical non-metal. H exists in two allotropic forms. The compounds of boron are mainly electron deficient as well as Lewis acids. For example, all the trihalides of boron (BX_(3)) are Lewis acids. The expected order of acidic strength based on the electro negativity of halogen atoms is : BF_(3)gtBC l_(3)gtBBr_(3)gtBl_(3) . But the actual order is the reverse. This is explained with the help of the concept of back bonding (p pi- p pi) . Among the hydrides of boron. diborane has a bridged structure. Among the halides of the elements of group 13, the one which is most acidic is:

Complete the following crossword puzzle (Figure) Across (1) An element with atomic number 12 (3) Metal used in making cans and member of group 14 (4) A lustrous non-metal which has 7 electrons in its outermost shell Down (2) Highly reactive and soft metal which imparts yellow colour when subjected to flame and is kept in kerosene (5) The first element of second period (6) An element whihc is used in making flurescent bulbs and is second member of group 18 in the modern periodic table (7) A radioactive element which is the last member of halogen family (8) Metal which is an important constituent of steel and forms rust when exposed to moist air (9) The first metalloid in modern periodic table whose fibres are used in making bullet-proof vests

DINESH PUBLICATION-P BLOCK ELEMENTS (GROUP 13 AND 14 )-Short answer type
  1. Give reasons for the following (a) C Cl(4) is immiscible in water, w...

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  2. Explain the following (a) CO(2) is a gas whereas SiO(2) is a solid ...

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  3. The +1 oxidation state in group 13 and +2 oxidation state in group 14 ...

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  4. Carbon and silicon both belong to the group 14, but inspite of the sto...

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  5. If a trivalent atom replaces a few silicon atoms in three dimensional ...

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  6. When BCl(3) is treated with water, it hydrolyses and forms [B(OH)(4)]^...

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  7. Aluminium dissovles in mineral acids and aqueous alkalies and thus sho...

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  8. Explain the following : (a) Boron has high melting and boiling point...

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  9. Identify the compound A, X and Z in the following reactions: (i) A+2...

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  10. Complete the following chemical equations: (i) z+3LiAlH(4)rarrX+3Li...

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  11. Describe the general trends in the following properties of the element...

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  12. Account for the following observation: (i) AlCl(3) is Lewis acid (...

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  13. When aqueous solution of borax is acidified with hydrochloric acid, a ...

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  14. Three pairs of compounds are given below, identify that compound in e...

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  15. BCl(3) exists as monomer whereas AlCl(3) is dimerised through halogen ...

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  16. Explain why BF(3) exist but BH(3) does not.

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  17. What are silicones ?

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  18. A compound (A) of boron reacts with Nme(3) to give an adduct (B) which...

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  19. A non-metallic element of group 13, used in making bullet prrof vests ...

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  20. A tetravalent element forms monoxide and dioxide with oxygen. When air...

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