Home
Class 12
CHEMISTRY
In PCl(5), phosphorus is in sp^(3) d hyb...

In `PCl_(5)`, phosphorus is in `sp^(3)` d hybridised state but all its five bonds are not equivalent. Justify your answer with reason.

Text Solution

Verified by Experts

`PCl_(5)` molecule has trigonal bipyramidal geometry in which the central atom is linked with three P - F equitorial bonds and two P - F axial bond. Since these bonds have different bond lengths, these are not same.
Promotional Banner

Topper's Solved these Questions

  • THE P-BLOCK ELEMENTS

    DINESH PUBLICATION|Exercise Long Answer Type Questions|3 Videos

  • THE P-BLOCK ELEMENTS

    DINESH PUBLICATION|Exercise Questions From Board Examinations|122 Videos

  • THE P-BLOCK ELEMENTS

    DINESH PUBLICATION|Exercise N.C.E.R.T. Exercise|40 Videos

  • THE OXYGEN FAMILY

    DINESH PUBLICATION|Exercise PREPARATORY PACKAGE|14 Videos

Similar Questions

Explore conceptually related problems

(a) Why does PCl_3 fume in moisture ? (b) Are all the five bonds in PCl_5 molecule equivalent ? Justify your answer. ( c) How do you account for the reducing behaviour of H_3 PO_2 on the basic of its structure ? (d) Give the disproportional reaction of H_3PO_3 .

All bonds in the molecule of PCl_(5) are not equivalent. Explain.

The hybrid states of phosphorous atoms in each PCl_(5) and PBr_(5) in gasesous phase are sp^(3)d . But, in solid PCl_(5) ,phosphorous shows sp^(3)d^(2) and sp^(3) hybrid states. While,P in PBr_(5) is in sp^(3) hybrid state. This is because:

All five bonds of PCl_(5) are not equilvalent and PCl_(5) is less stable. Explain.

Explain the structure of PCl_(5) according to hybridization. Why all P – Cl bonds lengths are not equivalent in PCl_(5) ?

DINESH PUBLICATION-THE P-BLOCK ELEMENTS -Short Answer Type Questions
  1. Write a balanced chemical equation for the reaction showing catalytic ...

    Text Solution

    |

  2. Write the structure of pyrophosphoric acid.

    Text Solution

    |

  3. PH(3) forms bubbles when passed slowly in water but NH(3) dissolves. E...

    Text Solution

    |

  4. In PCl(5), phosphorus is in sp^(3) d hybridised state but all its five...

    Text Solution

    |

  5. Why is nitric oxide paramagnetic in gaseous state but the solid obtain...

    Text Solution

    |

  6. Give reason to explain why ClF(3) exists but FCl(3) does not exist.

    Text Solution

    |

  7. Out of H(2)O " and " H(2)S, which one has higher bond angle and why ?

    Text Solution

    |

  8. SF(6) is known but SC(6) is not. Why?

    Text Solution

    |

  9. On reaction with Cl(2) phosphorus forms two types of halides 'A' and '...

    Text Solution

    |

  10. In the ring test of NO(3)^(-) ion, Fe^(2+) ion reduces nitrate ion to ...

    Text Solution

    |

  11. Explain why the stability of oxoacids of chlorine increases in the ord...

    Text Solution

    |

  12. Explain why ozone is thermodynamically less stable then oxgen ?

    Text Solution

    |

  13. P(4)O(6) reacts with water according to equation P(4)O(6)to4H(3)PO(3)....

    Text Solution

    |

  14. White phosphorus reacts with chlorine and the product hydrolyses in th...

    Text Solution

    |

  15. Name three oxoacids of nitrogen . Write the disproportionation reactio...

    Text Solution

    |

  16. Nitric acid forms an oxide of nitrogen on reaction with P(4)O(10). Wri...

    Text Solution

    |

  17. Phosphorus has three allotropic forms (i) white phosphorus (ii) red p...

    Text Solution

    |

  18. Given an example to show the effect of concentration of nitric acid on...

    Text Solution

    |

  19. PCl(5) reacts with finely divided silver on heating and a white silver...

    Text Solution

    |

  20. Phosphorus forms a number of oxoacids. Out of these oxoacids, phosphin...

    Text Solution

    |