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ZnO is white cold and yellow when heated...

`ZnO` is white cold and yellow when heated, it is due to the development of

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`Zn^(2+)` ion (ZnO) has `3d^(10)` electronic configuration with all the electrons paired. Therefore, ZnO is white. The yellow colour of Zno is due to non-stoichiometric defect leading to extra cation at the interstital sites.
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In an ideal crystal, the entropy of the constituents at absolute zero temperature (0K) is zero. However, the crystals generally suffer from certain defects also called imperfections They may be both electronic and atomic in nature. The atomic imperfections may be stoichiometric (Schottky and Frenkel defects) or non-stoichiometric (metal excees and metal deficiency defects). In addition to these, there are impurity defects which are caused by the addition of certain impurities of metals and this is known as dopping. The dopping leads to semi conductors which may be either n-type or p-type in nature. Zinc oxide (ZnO) is white when cold and yellow when hot. It is due to the development of :

Assertion : ZnO becomes yellow when it is beated Reason: NaCI becomes yellow when heater in the presence of Na vapours due to anion vacancy

ZnO shows yellow colour on heating due to

DINESH PUBLICATION-D-AND -F BLOCK ELEMENTS-Additional Important Question
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  2. Which of the following element form interstitial compounds?

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  4. Calculate equivalent weight of Cu in CuO and Cu(2)O. At.wt. of Cu=63.6...

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  5. Out of Co^(2+) and Ni^(2+) ions, which has lower magnetic moment ?

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  7. Zn^(2+) salt are white while Cu^(2+) salts are blue. Assign reason.

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  8. Out of Fe^(2+) and Fe^(3+) ions, which is more stable ?

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  9. Anhydrous ferric chloride is prepared by:

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  16. Copper (I) is diamagnetic while copper (II) is paramagnetic . Explain...

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  18. Why do transition metals form coloured complexes ?

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