Home
Class 12
CHEMISTRY
The colour of the coordination compounds...

The colour of the coordination compounds depends on the crystal field splitting. What will be the correct order of absorption of wavelength of light of the visible region, for the complexes, `[Co(NH_(3)_(6)]^(3+). [Co(CN)_(6)]^(3+). [Co(H_(2)O)_(6)]^(3+)`

A

`[Co)CN)_(6)]^(3-) gt [Co(NH_(3))_(6)]^(3+) gt [Co(H_(2)O)_(6)]^(3+)`

B

`[Co(NH_(3))_(6)]^(3+) gt [Co(H_(2)O)_(6)]^(3+) gt [Co(CN)_(6)]^(3-)`

C

`[CoH_(2)O)_(6)]^(3+) gt Co(NH_(3))_(6)]^(3+) gt [Co(CN)_(6)]^(3-)`

D

`[Co(CN)_(6)]^(3-) gt [Co(NH_(3))_()]^(3+) gt [Co(H_(2)O)_(6)]^(3+)`

Text Solution

Verified by Experts

The correct Answer is:
C

all are octahedral complexes of `Co^(3-)` ion. The order of absorption of wavelength of light by different ligands is according to spectrochemical series.
Promotional Banner

Topper's Solved these Questions

  • CO-ORDINATION COMPOUNDS

    DINESH PUBLICATION|Exercise Matching Type questions|10 Videos
  • CO-ORDINATION COMPOUNDS

    DINESH PUBLICATION|Exercise Short Answer Type Questions|12 Videos
  • CO-ORDINATION COMPOUNDS

    DINESH PUBLICATION|Exercise NCERT exercise|32 Videos
  • CHEMISTRY IN EVERY DAY LIFE

    DINESH PUBLICATION|Exercise Unit test-9|50 Videos
  • CYANIDES, ISOCYANIDES, NITROCOMPOUNDS AND AMINES

    DINESH PUBLICATION|Exercise Unit test - 8|20 Videos

Similar Questions

Explore conceptually related problems

The colour of the coordination compounds depends on the crystal field splitting . What will be the correct order of obsorption of wavelength of light in the visible region, for the comolexes, [Co(NH_(3))_(6)]^(3+) m and [Co(H_(2)O)_(6)^(3+) ?

What will be the correct order for the wavelengths of absorption in the visible region for the following: [Ni(NO_(2))_(6)]^(4-), [Ni(NH_(3))_(6)]^(2+), [Ni(H_(2)O)_(6)]^(2+) ?

Correct increasing order for the wavelength of absorption in the visible region for the complexes of Co^(3+) is:

DINESH PUBLICATION-CO-ORDINATION COMPOUNDS -Multiple choise questions
  1. Which of the following complexes formed by Cu^(2+) ions is most stable...

    Text Solution

    |

  2. The colour of the coordination compounds depends on the crystal field ...

    Text Solution

    |

  3. When 0.1 mol CoCl(3)(NH(3))(5) is treated with excess of AgNO(3), 0.2 ...

    Text Solution

    |

  4. When 1 mol CrCl(3).6H(2)O is treated with excess of AgNO(3), 3 mol of ...

    Text Solution

    |

  5. The correct IUPAC name of [Pt(NH(3))(2)Cl(2)] is

    Text Solution

    |

  6. The stabilization of coordination compound due to chelation is called ...

    Text Solution

    |

  7. Indicate the complex ion which shows geometrical isomerism.

    Text Solution

    |

  8. The CFSE for octahedral [CoCl(6)]^(4-) is 18,000 cm^(-1). The CFSE for...

    Text Solution

    |

  9. Due to the presence of ambidenate ligands coordination compounds show ...

    Text Solution

    |

  10. The two compounds [Co(SO(4))(NH(3))(5)]Br and [Co(SO(4))(NH(3))(5)]Cl ...

    Text Solution

    |

  11. A chelating agent has two or more than two donor atoms to bind to a si...

    Text Solution

    |

  12. Which of the following species is not expected to be a ligand?

    Text Solution

    |

  13. What kind of the following species is not expand to be a ligand?

    Text Solution

    |

  14. IUPAC name of [Pt(NH(3))(2)Cl(NO(2))] is

    Text Solution

    |

  15. Atomic number of Mn. Fe and Co are 25, 26 and 27 respectively. Which o...

    Text Solution

    |

  16. Atomic number of Mn, Fe, Co and Ni are 25, 26, 27 and 28 respectively....

    Text Solution

    |

  17. Which of the following options are correct for [Fe(CN)(6)]^(3-) comple...

    Text Solution

    |

  18. An aqueous pink solution of cobalt (II) chloride changes to deep blue ...

    Text Solution

    |

  19. Which of the following complexes are homoleptic ?

    Text Solution

    |

  20. Which of the following complexes are heteroleptic ?

    Text Solution

    |