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An aqueous pink solution of cobalt (II) ...

An aqueous pink solution of cobalt (II) chloride changes to deep blue on addition of excess of `HCl`. This is because ....... .

A

`[Co(H_(2)O)_(6)]^(2+)` is transformed into `[CoCl_(6)]^(4-)`

B

`[Co(H_(2)O)_(6)]^(2+)` is transformed into `[CoCl_(4)]^(2+)`

C

`tetrahedral complexes have smaller crystal field splitting than octahedral complexes.

D

tetrahedral complexes have larger crystal field splitting than octahedral complex.

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The correct Answer is:
B, C

b,c are both correct options.
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Colour of cobalt chloride solution is:

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An aqueous solution of inorganic compounds (X) gives following reactions. (i) With an aqueous solution of barium chloride a precipitate insoluble in dilute HCl is obtained. (ii) Addition of excess of Kl gives a brown precipitate which turns white on additon of excess of hyposolution. (iii) With an aqueous solution of K_(4)[Fe(CN)_(6) , a brown coloured precipitate is obtained. Identity (X) and gives equation for the reaction for (i),(ii) and (iii) observations.

When concentrated HCI is added to an aqueous solution of CoCl_(2) . Its colour changes from reddish pink to deep blue . Which complex ion gives blue colour in this reaction ?

DINESH PUBLICATION-CO-ORDINATION COMPOUNDS -Multiple choise questions
  1. When 1 mol CrCl(3).6H(2)O is treated with excess of AgNO(3), 3 mol of ...

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  2. The correct IUPAC name of [Pt(NH(3))(2)Cl(2)] is

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  3. The stabilization of coordination compound due to chelation is called ...

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  4. Indicate the complex ion which shows geometrical isomerism.

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  5. The CFSE for octahedral [CoCl(6)]^(4-) is 18,000 cm^(-1). The CFSE for...

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  6. Due to the presence of ambidenate ligands coordination compounds show ...

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  7. The two compounds [Co(SO(4))(NH(3))(5)]Br and [Co(SO(4))(NH(3))(5)]Cl ...

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  8. A chelating agent has two or more than two donor atoms to bind to a si...

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  9. Which of the following species is not expected to be a ligand?

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  10. What kind of the following species is not expand to be a ligand?

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  11. IUPAC name of [Pt(NH(3))(2)Cl(NO(2))] is

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  12. Atomic number of Mn. Fe and Co are 25, 26 and 27 respectively. Which o...

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  13. Atomic number of Mn, Fe, Co and Ni are 25, 26, 27 and 28 respectively....

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  14. Which of the following options are correct for [Fe(CN)(6)]^(3-) comple...

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  15. An aqueous pink solution of cobalt (II) chloride changes to deep blue ...

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  16. Which of the following complexes are homoleptic ?

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  17. Which of the following complexes are heteroleptic ?

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  18. Identify the optically active compounds from the following

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  19. Identify the correct statements for the behaviour of ethane-1, 2-diami...

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  20. Which of the following complexes show linkage isomerism ?

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