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What is the correct order of atomic/ioni...

What is the correct order of atomic/ionic size ?

A

`Cu^(+) lt Cu lt Zn^(2+) lt Ag`

B

`Zn^(2+) lt Cu^(+) lt Cu lt Ag`

C

`Ag lt Cu lt Cu^(+) lt Zn^(2+)`

D

`Cu^(+) lt Zn^(2+) lt Cu lt Ag`

Text Solution

Verified by Experts

The correct Answer is:
B

Neutral atom tend to increases size down the group and across a period due to electromagnetic interaction between electrons in an atom modify the `Z_("eff")`.
`Z_("eff") = Z-S`= sheilding effect
As an additional electrons occupies the electrons in outer shell and protons in the nucleus. So, the `Z_("eff")` increases.
As an neutral atoms that have lost an `e^(-)` exhibit a positive charge and are called cations and therefore `Z_("eff")` increases.
So, the order of ionic radii is `Zn^(2+) lt Cu^(+) lt CU lt Ag`.
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