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Identify the pair that is not isostructu...

Identify the pair that is not isostructural

A

`PCl_(5), BrF_(5)`

B

`CH_(4), SiCl_(4)`

C

`CSO_(3)^(2-), NO_(3)^(-)`

D

`AlFS_(6)^(3-), SF_(6)`

Text Solution

Verified by Experts

The correct Answer is:
A

Isostructural species have same shape and hybridisation. Accept `PCl_(5), BrF_(5)` all species are is isostructural. `PCl_(5)`-trigonal bipyramidal shape `sp^(3)d`
`BrF_(5)`-square pyramidal shape `sp^(3) d^(2)`
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