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The potential of hydrogen electrode of p...

The potential of hydrogen electrode of pH = 10 with respect to standard hydrogen electrode is

A

`-0.0591V`

B

`-0.591V`

C

0.2V

D

0

Text Solution

Verified by Experts

The correct Answer is:
B

For, hydrogen electrode
`pH = 10 [H^(+)] = 10^(-10) M H^(+) + e^(-) = (1)/(2) H_(2)`
`E_("cell") = E^(@) - (0.0591)/(1) "log" ([H_(2)])/([H^(+)])`
`E^(@) = 0, log H_(2) = 0` because
`E_("cell") = - (0.0591)/(1) log ((1)/(10^(-10))) - 0.0591 xx 10`
`E_("cell") = - 0.591V`
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