298 K पर निम्न का इलेक्ट्रोड विभव निकालिए
`Pt, CI_(2)(2.5 atm) //HCI (0.01 M), E^(0)CI_(2)//2Cl^(-) = 1.35V `

Explanation

`Cl_(2) + 2e^(-) rarr 2Cl^(-)`
`E_(Cl_(2)//2Cl^(-)) = E^(0)_(Cl_(2)//2Cl^(-)) + 0.059/n logP_(Cl_(2))/[Cl^(-)]^(2)`
`P_(Cl_(2))= 2.5`
`E_(Cl_(2)//2Cl^(-)) = 1.35 + 0.059/2 log 2.5/(0.01)^(2)`
`= 1.35 + 0.059/2 log 0.01 xx 0.01/2.5`
`E_(Cl_(2)//2Cl^(-)) = 1.35 - 0.059/2 log(10^(-4))/2.5`
`= 1.35 - 0.059/2 [4 - 0.3979]`
`= 1.35 - 0.059/2 xx (-4.3979)`
= 1.35 + 0.1297 = 1.48 V