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For a reaction of type aA+bBrarr"pro...

For a reaction of type
`aA+bBrarr"products", (-d[A])/(dt)` is equal to

A

`(-d[B])/(dt)`

B

`-b/d(d[B])/(dt)`

C

`-a/(b)xx(d[B])/(dt)`

D

`-b/(a)xx(d[B])/(dt)`

Text Solution

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The correct Answer is:
To solve the question regarding the reaction of type \( aA + bB \rightarrow \text{products} \) and to express \(-\frac{d[A]}{dt}\) in terms of the stoichiometric coefficients, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding the Reaction**: The reaction is given as \( aA + bB \rightarrow \text{products} \). Here, \( A \) and \( B \) are the reactants, and \( a \) and \( b \) are their respective stoichiometric coefficients. 2. **Rate of Reaction**: The rate of reaction can be expressed in terms of the change in concentration of the reactants over time. For reactant \( A \), the rate of disappearance is given by: \[ -\frac{d[A]}{dt} \] For reactant \( B \), the rate of disappearance is: \[ -\frac{d[B]}{dt} \] 3. **Relating Rates to Stoichiometry**: The relationship between the rates of disappearance of the reactants and the formation of products can be expressed using their stoichiometric coefficients: \[ -\frac{1}{a} \frac{d[A]}{dt} = -\frac{1}{b} \frac{d[B]}{dt} \] This means that the rate of disappearance of \( A \) is proportional to its stoichiometric coefficient \( a \), and similarly for \( B \) with coefficient \( b \). 4. **Expressing \(-\frac{d[A]}{dt}\)**: Rearranging the above equation gives: \[ -\frac{d[A]}{dt} = \frac{a}{b} \left(-\frac{d[B]}{dt}\right) \] This indicates that the rate of disappearance of \( A \) can be expressed in terms of the rate of disappearance of \( B \) and their stoichiometric coefficients. 5. **Final Expression**: Thus, the expression for \(-\frac{d[A]}{dt}\) in terms of the concentration change of \( B \) is: \[ -\frac{d[A]}{dt} = \frac{a}{b} \left(-\frac{d[B]}{dt}\right) \]
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AAKASH INSTITUTE-CHEMICAL KINETICS-ASSIGNMENT (SECTION A : Objective Type Questions)
  1. The unit of rate constant and rate of a reaction are same for

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  2. For a reaction of type aA+bBrarr"products", (-d[A])/(dt) is equal ...

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  3. For a gaseous reaction, the rate of reaction may be expressed in the u...

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  4. In gaseous state reaction, A(2)(g)rarrB(g)+((1)/(2))C(g). The increase...

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  5. Which of the following will react at the highest rate ?

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  6. Which of the following does not affect the rate of reaction?

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  7. In a reaction, 2X + Y rarrX2Y , the X disappears at

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  8. During the course of a chemical reaction , the rate constant .

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  9. A reaction involiving two different reactants can never be:

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  10. For the hypothetical reaction 2A rarr3C , the reaction rate r in term...

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  11. In the reaction A +2B rarr C +2O the initial rate (-d[A])/(dt) at t=0w...

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  12. For the reaction N(2) + 3 H(2) to 2 NH(3) The rate of change of conc...

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  13. The graph plotted between concentration versus time

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  14. For reaction, 2B+A rarr 2C Which of the following is correct ?

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  15. For the homogeneous elementary reaction, A+B rarrC, the unit of rate ...

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  16. The rate law for a reaction between the substances A and B is given by...

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  17. Consider the reaction, 2A + B rarr C + D , If the rate expression is...

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  18. The rate constant is numerically the same for three reaction of first ...

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  19. Assuring an elementary reaction H2O2+3I^(-)+2H^(+)rarr2H2O+I3^(-) . Th...

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  20. For a reaction A+B rarr products, the rate of reaction was doubled whe...

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