Home
Class 12
CHEMISTRY
At temperature above 85 K, decarboxylati...

At temperature above 85 K, decarboxylation of acetic acid becomes a spontaneous process under standard state conditions. What is the standard entropy change (in J/K-mol) of the reaction.
`CH_(3)COOH (aq) rarr CH_(4)(g) +CO_(2)(g)`
`{:("Given :",DeltaH_(f)^(@)[CH_(3)COOH (aq)],=-484" kJ/mole"),(,DeltaH_(f)^(@)[CO_(2)(g)],=-392" kJ/mole"),(,DeltaH_(f)^(@)[CH_(4)(g)],=-75" kJ/mole"):}`

Text Solution

Verified by Experts

The correct Answer is:
200 J/K mole

`DeltaS=(DeltaH)/(T) =(-392-75-(-484))/(85) =200 J//K` mole
Promotional Banner

Topper's Solved these Questions

Similar Questions

Explore conceptually related problems

At temperature above 85 K, decarboxylation of acetic becomes a spontaneous process under standard state conditions. What is the standard entropy change (in J/K-mol) of the reaction. CH_(3)COOH (aq) rarr CH_(4)(g)+CO_(2)(g) {:("Given :",DeltaH_(f)^(@)[CH_(3)COOH (aq)],=-484" kJ/mole"),(,DeltaH_(f)^(@)[CO_(2)(g)],=-392" kJ/mole"),(,DeltaH_(f)^(@) [CH_(4)(g)],=-75" kJ/mole"):}

For the reaction 3N_(2)O(g)+2NH_(3)(g)to4N_(2)(g)+3H_(2)O(g),DeltaH^(@)=-879.6kJ If DeltaH_(f)^(@)[NH_(3)(g)]=-45.9kJ" "mol^(-1) , DeltaH_(f)^(@)[H_(2)O(g)]=-241.8kJ" "mol^(-1) Then DeltaH_(f)^(@)[N_(2)O(g)] will be:

Calculate the standard enthalpy of reaction ZnO(s)+CO(g)rarrZn(s)+CO_(2)(g) Given, Delta H_(f)(ZnO,s)=-350KJ//"mole",DeltaH_(f)^(@)(CO_(2),g)= -390KJ//"mole", DeltaH_(f)^(@)(CO,g)=-110KJ//"mole"

Determine the enthalpy of formation of B_(2)H_(6) (g) in kJ/mol of the following reaction : B_(2)H_(6)(g)+3O_(2)(g)rarrB_(2)O_(3)(s)+3H_(2)O(g) , Given : Delta_(r )H^(@)=-1941 " kJ"//"mol", " "DeltaH_(f)^(@)(B_(2)O_(3),s)=-1273" kJ"//"mol," DeltaH_(f)^(@)(H_(2)O,g)=-241.8 " kJ"//"mol"

The standard enthalpy of formation of ammonia gas is Given: N_(2)H_(4) (g) + H_(2) (g) rarr 2NH_(3) (g), Delta H_(r)^(@) = - 40 kJ//mol DeltaH_(f)^(@) [N_(2)H_(4) (g)] = - 120 kJ//mol

Calculate C-H bond energy from the following data : Delta_(f)H" "[C(g)]=716.68 kJ//"mole" Delta_(f)H" "[H(g)]=217.97 kJ//"mole" Delta_(f)H" "[CH_(4)(g)]=-74.81 kJ//"mole"

Use the given standard enthalpies of formation (in kJ/mol) to determine the enthalpy of reaction of the following reaction : NH_(3)(g)+3F_(2)(g)rarrNF_(3)+3HF(g) DeltaH_(f)^(@)(NH_(3),g)=-46.2, " "DeltaH_(f)^(@)(NF_(3),g)=-113.0 ," "DeltaH_(f)^(@)(HF, g)=-269.0

BANSAL-THERMOCHEMISTRY-Exercise 3
  1. Benzoic acid is a common standard used in Bomb calorimaters, which mai...

    Text Solution

    |

  2. Calculate the electron gain enthalpy of fluorine atom using the follow...

    Text Solution

    |

  3. The Born -Haber cycle for formation of rubidium chloride (RbCl) is giv...

    Text Solution

    |

  4. The enthalpy of formation of ethane, ethylene and benzene from the gas...

    Text Solution

    |

  5. Calculate the enthalpy of combustion of methyl alcohol at 298 K fr...

    Text Solution

    |

  6. Using the data given below, establish that the vapourisation of C Cl(4...

    Text Solution

    |

  7. From the given table answer the following question: {:(,CO(g),CO(2)(...

    Text Solution

    |

  8. At temperature above 85 K, decarboxylation of acetic acid becomes a sp...

    Text Solution

    |

  9. By using the following data draw an appropriate enthalpy cycle & Calcu...

    Text Solution

    |

  10. Calculate the heat produced when 3.785 litre of actane (C(8)H(18)) rea...

    Text Solution

    |

  11. Calculate the enthalpy of combustion of benzene (l) on the basis of th...

    Text Solution

    |

  12. The enthalpy of formation of C(2)H(5)OH(l) is -66 k Cal//mol. The enth...

    Text Solution

    |

  13. A person takes 15 breaths per minute. The volume of air inhaled in eac...

    Text Solution

    |

  14. The standard enthalpy of combustion of sucrose is -5645 kJ mol^(-1). W...

    Text Solution

    |

  15. The enthalpies of neutralization of a weak acid HA & a weak acid HB by...

    Text Solution

    |

  16. Calculate the mass of mercury which can be liberated from HgO at 25^(@...

    Text Solution

    |

  17. An intimate mixture of ferric oxide and aluminium is used as solid fue...

    Text Solution

    |

  18. Calculate the enthalpy change for the following reaction: XeF(4) rar...

    Text Solution

    |

  19. During one of his adventure Chacha Chaudhary got trapped in an undergr...

    Text Solution

    |

  20. For an ionic solid MX(2), where X is monovalent, the enthalpy of forma...

    Text Solution

    |