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What will be the % labelling of oleum co...

What will be the % labelling of oleum containing `40% SO_(3)` by mass ?

A

109

B

118

C

113.5

D

122.5

Text Solution

Verified by Experts

The correct Answer is:
A

40% by mass `SO_(3)`
40 gm `SO_(3)` in 100 gm Oleum
Hence 109% labelled oleum
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Find the % labeiling of 100gm oleum sample if it contains 20gm SO_(3) .

Oleum or fuming sulphuric acid contains SO_(3) dissolved in sulphuric acid and has the molecular formula H_(2)S_(2)O_(7) , It is formed by passing SO_(3) in H_(2)SO_(4) . When water is added to oleum, SO_(3) reacts with water to form H_(2)SO_(4) . SO_(3)(g) + H_(2)O(l) to H_(2)SO_(4)(aq) As a result, mass of H_(2)SO_(4) increases. When 100 g sample of oleum is diluted with desired amount of water (in gram) then the total mass of pure H_(2)SO_(4) obtained after dilution is known as percentage labelling of oleum. % Labelling of oleum = Total mass of H_(2)SO_(4) present in oleum after dilution or = Mass of H_(2)SO_(4) initially present + Mass of H_(2)SO_(4) produced after dilution From this, the percentage composition of H_(2)SO_(4) and SO_(3) (free) and SO_(3) (combined) can be calculated. The percentage of free SO_(3) and H_(2)SO_(4) in 112% H_(2)SO_(4) is

Oleum or fuming sulphuric acid contains SO_(3) dissolved in sulphuric acid and has the molecular formula H_(2)S_(2)O_(7) , It is formed by passing SO_(3) in H_(2)SO_(4) . When water is added to oleum, SO_(3) reacts with water to form H_(2)SO_(4) . SO_(3)(g) + H_(2)O(l) to H_(2)SO_(4)(aq) As a result, mass of H_(2)SO_(4) increases. When 100 g sample of oleum is diluted with desired amount of water (in gram) then the total mass of pure H_(2)SO_(4) obtained after dilution is known as percentage labelling of oleum. % Labelling of oleum = Total mass of H_(2)SO_(4) present in oleum after dilution or = Mass of H_(2)SO_(4) initially present + Mass of H_(2)SO_(4) produced after dilution From this, the percentage composition of H_(2)SO_(4) and SO_(3) (free) and SO_(3) (combined) can be calculated. The percentage of SO_(3) in 109% H_(2)SO_(4) is

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