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What final product will form when alcoho...

What final product will form when alcoholic KOH is treated with 1,1- dirbomoethane ?

A

Ethene

B

Ethane -1, 2 - diol

C

Acetaldehyde

D

Ethyne

Text Solution

AI Generated Solution

The correct Answer is:
To determine the final product formed when 1,1-dibromoethane is treated with alcoholic KOH, we can follow these steps: ### Step 1: Identify the Reactants 1,1-Dibromoethane (C2H4Br2) is a compound with two bromine atoms attached to the first carbon atom of the ethane chain. Alcoholic KOH is a strong base that can facilitate elimination reactions. **Hint:** Look for the structure of 1,1-dibromoethane to visualize the bromine atoms' positions. ### Step 2: Understand the Reaction Type The reaction between 1,1-dibromoethane and alcoholic KOH is a dehydrohalogenation reaction. This means that the reaction will involve the elimination of hydrogen halides (HBr in this case). **Hint:** Remember that dehydrohalogenation typically leads to the formation of alkenes or alkynes. ### Step 3: Mechanism of the Reaction 1. The alcoholic KOH will act on the 1,1-dibromoethane. The potassium (K) will bond with one of the bromine (Br) atoms, leading to the elimination of KBr. 2. The hydroxide ion (OH-) will abstract a hydrogen atom from the adjacent carbon, resulting in the formation of a double bond. **Hint:** Focus on how the elimination of Br and H occurs to form a double bond. ### Step 4: First Elimination After the first elimination, we will have: - CH2=CHBr (vinyl bromide) **Hint:** Keep track of the changes in the molecular structure after each step. ### Step 5: Second Elimination Now, the vinyl bromide (CH2=CHBr) will undergo a similar reaction: 1. KOH will again react, with K bonding to Br and OH- taking H from the carbon adjacent to the Br. 2. This results in the formation of a triple bond. The final product after the second elimination will be: - C≡C (ethyne or acetylene) **Hint:** Consider the stability of the formed product and the type of bonds created during the reaction. ### Step 6: Identify Side Products Along with the main product (ethyne), the side products of the reaction will be: - 2 KBr (from the two eliminations) - 2 water molecules (from the hydroxide ions abstracting hydrogen) **Hint:** Always account for the by-products formed during the reaction. ### Conclusion The final product formed when 1,1-dibromoethane is treated with alcoholic KOH is ethyne (acetylene). The side products are KBr and water. **Final Answer:** Ethyne (C2H2) is the main product formed.
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