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Product of the given reaction CH3CH2-CH=...

Product of the given reaction `CH_3CH_2-CH=CH_3overset(SiO_2)rarr` will be

A

`CH_3-overset(OH)overset(|)(CH)-CH=CH_2`

B

`overset(OH)overset(|" ")(CH_2)-CH_2-CH=CH_2`

C

`CH_3-CH_2-underset(O)underset(||)C-CH_3`

D

`CH_3-CH_2-underset(O)underset(||)C-CHO`

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The correct Answer is:
To solve the reaction of 1-butene (CH₃CH₂-CH=CH₂) with SiO₂, we will follow these steps: ### Step 1: Identify the Reactant The reactant is 1-butene, which has the structure: \[ \text{CH}_3\text{CH}_2\text{CH}=\text{CH}_2 \] ### Step 2: Understand the Role of SiO₂ Silica (SiO₂) acts as a catalyst in this reaction and is known for facilitating selective hydroxylation, specifically allylic hydroxylation. This means that it will introduce a hydroxyl (-OH) group at the allylic position relative to the double bond. ### Step 3: Determine the Allylic Position In 1-butene, the double bond is between the second and third carbon atoms. The allylic positions are the carbon atoms adjacent to the double bond. Therefore, the allylic positions are: - The carbon atom at position 2 (CH₂) - The carbon atom at position 3 (CH) ### Step 4: Perform the Hydroxylation In allylic hydroxylation, the hydrogen atom from the allylic carbon (position 2) is replaced with a hydroxyl group (-OH). The reaction can be represented as follows: - The hydrogen atom from the second carbon (CH₂) is removed, and an -OH group is added. The product will then be: \[ \text{CH}_3\text{CHOH}\text{CH}=\text{CH}_2 \] ### Step 5: Write the Final Product Thus, the final product of the reaction is: \[ \text{CH}_3\text{CHOH}\text{CH}=\text{CH}_2 \] ### Conclusion The product of the reaction of 1-butene with SiO₂ is: \[ \text{CH}_3\text{CHOH}\text{CH}=\text{CH}_2 \]
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