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In the given reaction CH3-CH2-Broverset(...

In the given reaction `CH_3-CH_2-Broverset(Na//"dryether")rarr` Product, product will be

A

Pure n - butane

B

Mixture of butane and hydrogen

C

Mixture of butane, ethene and ethane

D

Mixture of ethene and ethane

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The correct Answer is:
To solve the given question regarding the reaction of `CH3-CH2-Br` with sodium in dry ether, we will follow these steps: ### Step 1: Identify the Reactants The reactant is `CH3-CH2-Br`, which is bromoethane. Sodium (Na) is used in the presence of dry ether. **Hint:** Recognize that sodium is a reducing agent and dry ether is a solvent that supports radical reactions. ### Step 2: Understand the Reaction Mechanism The reaction proceeds through a free radical mechanism. Sodium donates an electron to the bromine atom, generating a bromine radical and an ethyl radical. **Hint:** Remember that in free radical reactions, the breaking of a bond leads to the formation of radicals. ### Step 3: Formation of Radicals The ethyl radical (`CH3-CH2•`) can combine with another ethyl radical or react with other radicals formed during the reaction. **Hint:** Consider the possibility of radical recombination, which can lead to the formation of larger alkane chains or different products. ### Step 4: Possible Products 1. **Butane Formation**: The ethyl radical can combine with another ethyl radical to form butane (`CH3-CH2-CH2-CH3`). 2. **Ethylene Formation**: If two ethyl radicals combine in a different manner, they could also form ethylene (`CH2=CH2`). **Hint:** Think about the types of products that can arise from radical coupling and rearrangement. ### Step 5: Conclusion The primary product of the reaction will be butane, but ethylene can also be formed depending on the reaction conditions and the pathways taken by the radicals. **Final Answer:** The product will be butane (`C4H10`), with the possibility of ethylene (`C2H4`) as a minor product.
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