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In the given reaction CH3-CN+CH3CHOovers...

In the given reaction `CH_3-CN+CH_3CHOoverset(NaNH_2//NH_3(l))rarr(X),` (X) will be

A

`CH_3-overset(OH)overset(|)(CH)-CH_2-CN`

B

`{:(CH_3-C=NH),(" "|),(" "CH_2-CHO):}`

C

`CH_3-CH=CH-CN`

D

`CH_3-CH=CH-CHO`

Text Solution

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The correct Answer is:
To solve the reaction \( CH_3-CN + CH_3CHO \overset{NaNH_2/NH_3(l)}{\rightarrow} (X) \), we will follow these steps: ### Step 1: Identify the Reactants The reactants are acetonitrile (\( CH_3-CN \)) and acetaldehyde (\( CH_3CHO \)). ### Step 2: Role of Sodium Amide (NaNH2) Sodium amide (\( NaNH_2 \)) is a strong base. It will abstract a proton from the acetonitrile (\( CH_3-CN \)), converting it into an anion. The reaction can be represented as: \[ CH_3-CN + NaNH_2 \rightarrow CH_3-CN^- + Na^+ + NH_3 \] ### Step 3: Nucleophilic Attack The anion (\( CH_3-CN^- \)) formed will act as a nucleophile and attack the carbonyl carbon of acetaldehyde (\( CH_3CHO \)). The carbonyl carbon is electrophilic due to the partial positive charge on it. The reaction can be represented as: \[ CH_3-CN^- + CH_3CHO \rightarrow CH_3-C(OH)(CN)CH_3 \] ### Step 4: Proton Transfer After the nucleophilic attack, a proton transfer occurs. The hydroxyl group (OH) formed will take a proton from the surrounding medium, leading to the formation of a compound with a carbon-carbon bond and a hydroxyl group: \[ CH_3-C(OH)(CN)CH_3 \] ### Step 5: Elimination of Water Upon heating, the compound can undergo dehydration (loss of water) to form an unsaturated compound. The elimination of water (H and OH) from the intermediate will yield: \[ X = CH_3-CH=CH-CN \] ### Conclusion Thus, the final product \( X \) is: \[ X = CH_3-CH=CH-CN \]
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