Home
Class 12
CHEMISTRY
Consider the following reaction CH3-CH=C...

Consider the following reaction `CH_3-CH=CH_2overset(Br_2//NaCl)rarr` Product of the reaction will be

A

Only 1,2 - dibromopropane

B

Only 1- bromo -2- chloropropane

C

Only -2- bromo -1- chloropropane

D

Mixture of 1,2 dibromopropane and 1 - bromo -2- chloropropane

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the reaction of propene (CH₃-CH=CH₂) with bromine (Br₂) in the presence of sodium chloride (NaCl). Here’s a step-by-step breakdown of the reaction: ### Step 1: Identify the Reactants The reactants in this reaction are propene (CH₃-CH=CH₂) and bromine (Br₂) in the presence of sodium chloride (NaCl). **Hint:** Look at the structure of propene and note the presence of the double bond, which is reactive. ### Step 2: Mechanism of the Reaction When Br₂ is added to the alkene (propene), the double bond (π bond) attacks one of the bromine atoms. This leads to the formation of a bromonium ion intermediate. **Hint:** Remember that the π bond acts as a nucleophile and attacks the electrophilic Br₂. ### Step 3: Formation of the Bromonium Ion The attack of the π bond on Br₂ results in the formation of a cyclic bromonium ion. This intermediate has a positive charge on one carbon and a bromine atom attached to the other carbon. **Hint:** Visualize the bromonium ion as a three-membered ring where one carbon is bonded to a bromine atom. ### Step 4: Nucleophilic Attack by Chloride Ion In the presence of NaCl, the chloride ion (Cl⁻) can act as a nucleophile. It attacks the more substituted carbon of the bromonium ion from the opposite side (anti-addition). **Hint:** The chloride ion will attack the carbon that is more stable due to sterics, which is typically the more substituted carbon. ### Step 5: Final Product Formation After the nucleophilic attack by Cl⁻, we get two products: 1. 1-bromo-2-chloropropane (CH₃-CH(Cl)-CH₂Br) 2. 1,2-dibromopropane (CH₃-CH(Br)-CH₂Br) **Hint:** Consider that anti-addition leads to the formation of two different products due to the different positions of the halogens. ### Step 6: Conclusion The final products of the reaction are a mixture of 1-bromo-2-chloropropane and 1,2-dibromopropane. **Final Answer:** The correct option is that the product of the reaction will be a mixture of 1,2-Dibromo and 1-Bromo-2-Chloropropane.
Promotional Banner

Topper's Solved these Questions

  • NTA NEET SET 94

    NTA MOCK TESTS|Exercise CHEMISTRY|45 Videos
  • NTA NEET SET 96

    NTA MOCK TESTS|Exercise CHEMISTRY|45 Videos

Similar Questions

Explore conceptually related problems

Consider the following reaction CH_(3)-CH_(2)-CH_(2)-CH_(3)overset(AlCl_(3)//HCl)rarr product The reaction is named as

CH_3-CH=CH_2overset(HCl)rarr(A) . A is in the given reaction will be

Consider the following reaction: CH_(3)CH=CH_(2)overset(B_(2)H_(6))rarrAoverset(CH_(3)COOH)rarrB The end product is

Product of the given reaction CH_3CH_2-CH=CH_3overset(SiO_2)rarr will be

Product formed in the following reaction is CH_3CH_2CH(OH)CH_3overset(H_2SO_4)rarr

Consider the following sequence of reactions ltbRgt CH_(3)CH(OH)CH_(3)overset(NaH)(rarr)Aoverset(CH_(3)CH_(2)I)(rarr)B The product (B) is

Consider the reaction : CH_(3)CH_(2)CH_(2)Br+NaCNrarrCH_(3)CH_(2)CH_(2)CN+NaBr This reaction will be the fastest in :

CH_(3)CH=CH_(2)+BrC Cl_(3)overset("Peroxide")rarr The major product of the reaction is

NTA MOCK TESTS-NTA NEET SET 95-CHEMISTRY
  1. Which among the following is not an exact differential?

    Text Solution

    |

  2. Which of the following plot is correct about the kinetic energy of pho...

    Text Solution

    |

  3. Consider the following reaction CH3-CH=CH2overset(Br2//NaCl)rarr Produ...

    Text Solution

    |

  4. Which of the following combination does not evolve Cl(2) gas?

    Text Solution

    |

  5. Most acidic hydrogen is present in

    Text Solution

    |

  6. Consider the following reaction M+O2 rarrMO2 (M= alkali metal) (stable...

    Text Solution

    |

  7. Two isomeric compounds Cl-CH2-CH2-CH2Cl and CH3-CH2-CHCl2 can be dis...

    Text Solution

    |

  8. Which compound will liberate oxygen when reacts with ice cold water ?

    Text Solution

    |

  9. Which metal is protected by layer of its own oxide ?

    Text Solution

    |

  10. The pKb value of ammonium hydroxide is 4.75. An aqueous solution of am...

    Text Solution

    |

  11. In the given reaction [X] will be :

    Text Solution

    |

  12. Equilibrium constant for two complexes are A: K4[Fe(CN)6]2.6xx10^(37) ...

    Text Solution

    |

  13. the incorrect statement with respect to S(N^(1) " and " S(N^(2)) mech...

    Text Solution

    |

  14. Which of the following metals can be extracted by smelting ?

    Text Solution

    |

  15. A compound contains three elements A,B and C, if the oxidation number ...

    Text Solution

    |

  16. Which one of the following is an Z isomer ?

    Text Solution

    |

  17. Which of the following statement is correct ?

    Text Solution

    |

  18. Co-ordination number (CN) of barium ion (Ba^(2+)) in BaF^(2) is 8. Wha...

    Text Solution

    |

  19. If a 6.84%(wt,vol.)solutionof cane sugar(mol.Wt.=342)is isotonic with ...

    Text Solution

    |

  20. In the reaction X + Y underset(5^(@)C)overset(NaOH)(rarr) CH(3)-ov...

    Text Solution

    |