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For an exothermic reaction, following tw...

For an exothermic reaction, following two steps are involved.
`"Step 1. "A +B rarrI" (slow)"`
`"Step 2. "IrarrAB" (fast)"`
Which of the following graphs correctly represent this reaction ?

A

B

C

D

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The correct Answer is:
To solve the problem regarding the exothermic reaction with the given steps, we will analyze the reaction mechanism and how it reflects on a potential energy diagram. ### Step 1: Understand the Reaction Steps - The reaction consists of two steps: - **Step 1:** \( A + B \rightarrow I \) (slow) - **Step 2:** \( I \rightarrow AB \) (fast) ### Step 2: Identify the Nature of the Reaction - Since the reaction is exothermic, the overall energy of the products (AB) will be lower than that of the reactants (A + B). ### Step 3: Analyze the Energy Profile - In an energy profile diagram for a reaction: - The y-axis represents potential energy. - The x-axis represents the progress of the reaction. - For an exothermic reaction, the energy of the products is lower than that of the reactants. ### Step 4: Determine the Number of Maxima and Minima - The number of maxima in the energy diagram corresponds to the number of steps in the reaction mechanism. - In this case, there are two steps, so we expect two maxima (one for each step). - Between these two maxima, there will be a valley representing the stable intermediate \( I \). ### Step 5: Activation Energy Consideration - The activation energy for the slow step (Step 1) will be higher than for the fast step (Step 2). - This means that the first peak (for Step 1) will be higher than the second peak (for Step 2). ### Step 6: Conclusion - The correct graph must show: - Two peaks (maxima) corresponding to the two steps. - The first peak higher than the second peak. - The overall energy of the products lower than the reactants. ### Final Answer Based on the analysis, the correct graph that represents this exothermic reaction mechanism is **Option 2**.
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