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(A)(C(4)H(8)O)overset(H(3)O^(o+))rarr(B)...

`(A)(C_(4)H_(8)O)overset(H_(3)O^(o+))rarr(B)overset(CrO_(3))underset("acetic acid")rarr(C )overset(CH_(2)N_(2))underset(Delta)rarr(D)`
The compound 'D' is

A

B

C

D

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The correct Answer is:
To solve the question step by step, we will analyze the transformations of compound A (C₄H₈O) through the given reactions to determine the final product D. ### Step 1: Identify Compound A Given that A is C₄H₈O, we can start by calculating its degree of unsaturation (DOU) to understand its structure. **Degree of Unsaturation Calculation:** - Formula: DOU = (C + 1 - H + X - N) / 2 - For A (C₄H₈O): - C = 4 - H = 8 - X = 0 (no halogens) - N = 0 (no nitrogens) Plugging in the values: \[ DOU = (4 + 1 - 8 + 0 - 0) / 2 = (5 - 8) / 2 = -3 / 2 \] This indicates that there is one degree of unsaturation, suggesting that A is an unsaturated alcohol. ### Step 2: React A with H₃O⁺ When A reacts with H₃O⁺ (which provides H⁺ and water), it undergoes hydration to form an alcohol (B). The reaction mechanism involves protonation of the double bond, leading to the formation of a carbocation, which is then attacked by water. 1. Protonation of the double bond leads to the formation of a carbocation. 2. Water attacks the carbocation, resulting in the formation of an alcohol. Thus, compound B is an unsaturated alcohol derived from A. ### Step 3: React B with CrO₃ in Acetic Acid Next, B is reacted with CrO₃ in the presence of acetic acid, which acts as an oxidizing agent. Since B is an alcohol, it will be oxidized to a ketone. - The oxidation of the alcohol results in the formation of a carbonyl compound (C), specifically a cyclobutanone. ### Step 4: React C with CH₂N₂ (Diazomethane) Finally, compound C (cyclobutanone) is reacted with CH₂N₂ (diazomethane) under heating conditions. This reaction involves carbene insertion, where the carbene (generated from CH₂N₂) inserts into the carbonyl compound. 1. The carbene (CH₂) inserts into the C=O bond of cyclobutanone. 2. This results in the formation of cyclopentanone (D). ### Conclusion The final product D after all the reactions is cyclopentanone. ### Final Answer The compound 'D' is **cyclopentanone**. ---
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