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CuSO(4)(aq)overset(H(2)Suarr)rarrMdarrov...

`CuSO_(4)(aq)overset(H_(2)Suarr)rarrMdarroverset("Excess of KCN")rarrN+O`
Then final product N and O are respectively.

A

`[Cu(CN)_(4)]^(3-), (CN)_(2)`

B

`CuCN,(CN)_(2)`

C

`[Cu(CN)_(4)]^(2-), (CN)_(2)`

D

`Cu(CN)_(2), K_(2)S`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given problem, we will follow the reactions step by step. ### Step 1: Reaction of Copper Sulfate with Hydrogen Sulfide The first step involves the reaction of copper sulfate (CuSO₄) with hydrogen sulfide (H₂S). **Reaction:** \[ \text{CuSO}_4 (aq) + \text{H}_2\text{S} (g) \rightarrow \text{CuS} (s) + \text{H}_2\text{SO}_4 (aq) \] Here, copper(II) sulfide (CuS) is formed as a precipitate (M) along with sulfuric acid (H₂SO₄). ### Step 2: Reaction of Copper Sulfide with Excess Potassium Cyanide Next, we take the precipitated copper sulfide (CuS) and react it with excess potassium cyanide (KCN). **Reaction:** \[ \text{CuS} + 2 \text{KCN} \rightarrow \text{Cu(CN)}_2 + \text{K}_2\text{S} \] However, Cu(CN)₂ is not stable and will further dissociate into its components. ### Step 3: Formation of Final Products When Cu(CN)₂ is formed, it can further react with KCN to produce stable complexes. **Final Reaction:** \[ \text{Cu(CN)}_2 + \text{KCN} \rightarrow \text{CuCN} + \text{CN}^- \] Thus, the final products N and O are: - N = CuCN (copper(I) cyanide) - O = CN⁻ (cyanide ion) ### Summary of Final Products The final products N and O are: - N = CuCN - O = CN⁻
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