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In the reaction sequence C(6)H(5)CHO o...

In the reaction sequence
`C_(6)H_(5)CHO overset(NH_(2)OH//H^(o+))underset(Delta)rarr(X) overset(P_(2)O_(5)//Delta)rarr (Y) overset(H_(2)O//H^(o+))rarr(Z)`
(X), (Y) and (Z) respectively be

A

`C_(6)H_(5)CH=N-OH, C_(6)H_(5)CN, C_(6)H_(5)COOH`

B

`C_(6)H_(5)CH=NOH, C_(6)H_(5)CONH_(2),C_(6)H_(5)CONH_(2)`

C

`C_(6)H_(5)-CH=NOH, C_(6)H_(5)COOH, C_(6)H_(5)CONH_(2)`

D

`C_(6)H_(5)-CH=NOH, C_(6)H_(5)COOH, C_(6)H_(5)CN`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the reaction sequence given in the question, we will analyze each step carefully. ### Step-by-Step Solution: 1. **Identify the starting compound**: The starting compound is C₆H₅CHO, which is benzaldehyde. 2. **First Reaction with NH₂OH**: - Benzaldehyde reacts with hydroxylamine (NH₂OH) under heating conditions. - This reaction forms an oxime by the elimination of water (H₂O). - The structure of the oxime formed will be C₆H₅C=NOH. - Therefore, the product (X) is: \[ X = C_6H_5C=NOH \] 3. **Second Reaction with P₂O₅**: - The oxime (X) is then treated with phosphorus pentoxide (P₂O₅) and heated. - P₂O₅ is a dehydrating agent, which removes water from the oxime, converting it into a nitrile. - The product formed will be C₆H₅C≡N (benzonitrile). - Therefore, the product (Y) is: \[ Y = C_6H_5C≡N \] 4. **Third Reaction with H₂O**: - The nitrile (Y) undergoes hydrolysis in the presence of water (H₂O) and an acid (H⁺). - This hydrolysis converts the nitrile into a carboxylic acid. - The product formed will be C₆H₅COOH (benzoic acid). - Therefore, the product (Z) is: \[ Z = C_6H_5COOH \] ### Final Products: - (X) = C₆H₅C=NOH (Benzaldehyde oxime) - (Y) = C₆H₅C≡N (Benzonitrile) - (Z) = C₆H₅COOH (Benzoic acid) ### Summary of the Products: - **X** = C₆H₅C=NOH - **Y** = C₆H₅C≡N - **Z** = C₆H₅COOH
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