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In the given reaction C(6)H(5)-O-CH(2)-C...

In the given reaction `C_(6)H_(5)-O-CH_(2)-CH_(3)overset("Excess"Hl//Delta)rarr(X)+(Y)`
X and Y will respectively be

A

`C_(6)H_(5)I and CH_(3)-CH_(2)-I`

B

`C_(6)H_(5)-OH and CH_(3)-CH_(2)-I`

C

`C_(6)H_(5)I and CH_(3)-CH_(2)OH`

D

`C_(6)H_(5)OH and CH_(2)=CH_(2)`

Text Solution

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The correct Answer is:
To solve the given reaction \( C_6H_5OCH_2CH_3 \overset{\text{Excess } HI}{\rightarrow} (X) + (Y) \), we will analyze the reaction step by step. ### Step 1: Identify the Reactants The reactant is ethyl phenyl ether, which is represented as \( C_6H_5OCH_2CH_3 \). This compound consists of a phenyl group (\( C_6H_5 \)) attached to an ethyl group (\( CH_2CH_3 \)) via an oxygen atom. **Hint:** Look for the functional groups in the reactant to understand the reaction mechanism. ### Step 2: Understand the Role of Hydrogen Iodide (HI) Hydrogen iodide is a strong acid that can protonate the ether oxygen. In the presence of excess HI, the ether bond can be cleaved, leading to the formation of products. **Hint:** Consider how acids interact with ethers and what products can be formed from such reactions. ### Step 3: Protonation of the Ether When \( HI \) is added, the oxygen atom in the ether will be protonated, forming an oxonium ion. This makes the ether more reactive. **Hint:** Remember that protonation increases the electrophilicity of the ether. ### Step 4: Cleavage of the Ether The protonated ether can undergo cleavage. The bond between the oxygen and the ethyl group (\( CH_2CH_3 \)) is broken. This can lead to the formation of phenol and an alkyl iodide. **Hint:** Think about which bond is more likely to break based on stability and the nature of the groups involved. ### Step 5: Formation of Products After the cleavage, we will have two products: 1. Phenol (\( C_6H_5OH \)) from the phenyl group. 2. Ethyl iodide (\( CH_3CH_2I \)) from the ethyl group. Thus, we can identify: - \( X = C_6H_5OH \) (Phenol) - \( Y = CH_3CH_2I \) (Ethyl iodide) **Hint:** Check the structure of the products to ensure they match the expected outcome from the reaction. ### Conclusion The final products of the reaction are: - \( X = C_6H_5OH \) - \( Y = CH_3CH_2I \) ### Final Answer The products \( X \) and \( Y \) will respectively be: - \( X = C_6H_5OH \) (Phenol) - \( Y = CH_3CH_2I \) (Ethyl iodide)
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