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25 ml of H(2)O(2) solution was added to ...

25 ml of `H_(2)O_(2)` solution was added to the excess of acidified Kl solution . The iodine so liberated required 40 ml of `0.1` N sodium thiosulphate solution. Calculate the normality of `H_(2)O_(2)` solution :

A

`0.08`

B

`0.16`

C

`0.02`

D

`0.20`

Text Solution

Verified by Experts

The correct Answer is:
B

Let the normality of `H_(2)O_(2)` soln be`N_(x)`.
No. of milliequivalents of `Na_(2)S_(2)O_(3) ` = No. of milliequivalents of `H_(2)O_(2)`
`40 xx 0.1 = 25 xx N_(x)`
` N_(x) = (40 xx 0.1)/25 = 0.16` N
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25 mL of H_(2)O_(2) solution were added to excess of acidified solution of KI . The iodine so liberated required 20 mL of 0.1N Na_(2)S_(2)O_(3) for titration Calculate the strength of H_(2)O_(2) in terms of normalility, percentage and volumes. (b) To a 25 mL H_(2)O_(2) solution, excess of acidified solution of KI was added. The iodine liberated required 20 mL of 0.3N sodium thiosulphate solution. Calculate the volume strength of H_(2)O_(2) solution.

To a 25 mL H_(2)O_(2) solution excess of an acidified solution of potassium iodide was added. The iodine liberated required 20 " mL of " 0.3 N sodium thiosulphate solution Calculate the volume strength of H_(2)O_(2) solution.

To a 25 mL of H_(2)O_(2) solution, excess of acidified solution of KI was added. The iodine liberated required 20 mL of 0.3 N Na_(2)S_(2)O_(3) solution. Calculate the volume strength of H_(2)O_2 solution. Strategy : Volume strength of H_(2)O_(2) solution is related to its normality by the following relation Volume strength (V)=5.6xx"Normality" (N) where, Normality =((meq)H_(2)O_(2))/V_(mL) According to the law of equivalence (meq)_(Na_(2)S_(2)O_(3))=(meq)_(I_(2))=(meq)_(H_(2)O_(2))

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