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Metals are extracted from their ores by ...

Metals are extracted from their ores by a wide variety of techniques. The most common ores are oxides. Most metals are obtained by direct treatment of theirs ores with chemical agents, but the extraction of certain others require electrolysis. An example of the former type of process is the extraction of iron from its oxide, described by the following equation :
`Fe_(2) O_(3) + 3C rarr 2Fe + 3CO`
The relative ease of extraction of a metal from its oxide can be estimated using the Ellingham diagram, as shown in the figure.
The diagram plots the free energies of formation of various oxides per mole of consumed oxygen as a function of absolute temperature.

All of the following reagents could be used to extract lead from its oxide except

A

Molecular fluorine

B

Molecular boron

C

Molecular Nitrogen

D

Elemental carbon

Text Solution

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The correct Answer is:
A
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Knowledge Check

  • Metals are extracted from their ores by a wide variety of techniques. The most common ores are oxides. Most metals are obtained by direct treatment of theirs ores with chemical agents, but the extraction of certain others require electrolysis. An example of the former type of process is the extraction of iron from its oxide, described by the following equation : Fe_(2) O_(3) + 3C rarr 2Fe + 3CO The relative ease of extraction of a metal from its oxide can be estimated using the Ellingham diagram, as shown in the figure. The diagram plots the free energies of formation of various oxides per mole of consumed oxygen as a function of absolute temperature. Which of the following best explains why the free energy of formation of Fe_(2)O_(3) becomes less negative as the temperature is increased.

    A
    The free energy of formation is independent of the absolute temperature.
    B
    Entropy drops as a result of the consumption of oxygen.
    C
    At low temperature, the free energy of formation becomes less dependent on the enthalpy of formation.
    D
    As entropy increases, the free energy of formation increases.
  • Metals are extracted from their ores by a wide variety of techniques. The most common ores are oxides. Most metals are obtained by direct treatment of theirs ores with chemical agents, but the extraction of certain others require electrolysis. An example of the former type of process is the extraction of iron from its oxide, described by the following equation : Fe_(2) O_(3) + 3C rarr 2Fe + 3CO The relative ease of extraction of a metal from its oxide can be estimated using the Ellingham diagram, as shown in the figure. The diagram plots the free energies of formation of various oxides per mole of consumed oxygen as a function of absolute temperature. FIITJEE_CHE_MB_04_C02_E07_009_Q01.png" width="80%"> When ferric oxide is reduced to obtain iron metal, CO_(2) or CO can be produced. The production of CO_(2)

    A
    is directily proportional to the temperature
    B
    is inversely proportional to the temperature
    C
    is independent of the temperature
    D
    requires cooling of the CO
  • The extraction of metal from the ore is

    A
    an oxidation process
    B
    a reduction process
    C
    a hydration process
    D
    a neutratlisaiton process
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