A reaction of cobalt (III) chloride and ethylenediamine is a `1 : 2` mole ratio generates two isomeric products A (violet coloured) and B (green coloured). A can show optical activity, but, B is optically inactive. What type of isomers does A and B represent ?
When H_(2) is added to two isomeric alkenes A and B having molecular formula C_(5)H_(9)Cl , A gives optically inactive compound while B gives a chiral compound. The two isomers are
The compound Co(en)_(2)(NO_(2))_(2)CI has been prepared in these isomeric forms A,B and C A does not react with AgNO_(3) or (en) and is optically inactive B reacts with AgNO_(3) but not with (en) and is optically inactive C is optically active and reacts with both AgNO_(3) and (en) identify each of these isomeric forms and draw their structures .
An organic compound (A) contaning C, H, and O (16.32%) does not decolourise bromine water and does not give any precipitate with ammonical AgNO_(3) . It consumes 1 mol of NH_(2)OH per mole of (A) to give a solid derivative. The monobromo derivative of (A) shows optical activity. If (A) is optically inactive, suggest the structure.
