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Unlike phenols, alcohols are easily prot...

Unlike phenols, alcohols are easily protonated.

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Give possible explanation for the following. (a) Ortho-nitrophenol is more acidic than ortho-methoxyphenol. (b) Alcohols are easily protonated in comparision to phenols. (c) The relative ease of dehydration of alcohols is : tertiary gt secondary gt primary.

(i) Phenol has higher boiling point than toluene. Why? (ii) Why are alcohols easily protonated but phenols are not protonated?

Assertion: Alcohols are easily protonated thena phenols. Reason: Alcohols undergo intermolecular hydrogen bonding due to the presence of highly electornegative oxygen.

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