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Aldehydes and ketones give addition reac...

Aldehydes and ketones give addition reactions with

A

HCN

B

`NaHSO_(3)`

C

RMgX

D

ROH

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The correct Answer is:
A, B, C, D
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Both carbonyl compounds and acid derivatives though they contain grouping yet the reactions given by them are entirely different. As Aldehydes and Ketones give addition product with a nucleophile, while carboxylic acid derivatives give nucleophilic acyl substitution through addition/elimination mechanism. Where X- = -Cl - O-overset(O)overset(||)C-R-OR, -NR(R) etc. Why aldeydes and Ketones give nucleophilic addition reaction while acid derivatives prefer nucleophilic acyl substititution reaction?

FIITJEE-ALDEHYDES AND KETONES -ASSIGNMENT PROBLEMS (OBJECTIVE) LEVEL - II
  1. Which of the following undergoes aldol condensation?

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  2. Which of the following reactions are used for detecting presence of ca...

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  3. Aldehydes and ketones give addition reactions with

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  4. Which of the following reactions can be used to prepare acetophenone?

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  5. When a mixture of calcium acetate and calcium formate is heated, it yi...

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  6. Which statements are correct in the case of acetaldehyde and acetone ?

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  7. Which statements are correct in the case of acetaldehyde and acetone ?

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  8. Which statements are correct in the case of acetaldehyde and acetone

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  9. Which of the following will undergo aldol conddensation

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  10. The silver mirror with Tollen's reagent is formed by

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  11. Ethane can be prepared from ethanal in one step by the use of

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  12. When dry calcium formate is heated, it gives

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  13. The reaction of (CH(3))(3)CMgCl with (CH(3))(3)C-CO-C(CH(3))(3) after ...

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  14. Which of the following statements about benzaldehyde is/are true ?

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  15. Base-catalyzed aldol condensation occurs with

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  16. Which of the following compounds will give a yellow precipitate with ...

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  17. Benzophenone (C(6)H(5)COC(6)H(5)) does not react with

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  18. Which of the following are intermediates in the acid-catalysed reactio...

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  19. Which of the following are examples of aldol condensation ?

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  20. STATEMENT-1: Formaldehyde is more reactive than benzaldehyde for nucle...

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