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CH(3)-overset(O)overset(||)C-CH(3)+[O]ov...

`CH_(3)-overset(O)overset(||)C-CH_(3)+[O]overset(SeO_(2))rarrP+Se+H_(2)O`
Here P is

A

`CH_(3)COCHO`

B

`CH_(3)COOCH_(3)`

C

`CH_(3)COCH_(2)OH`

D

None

Text Solution

Verified by Experts

The correct Answer is:
A
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CH_(3)-overset(O)overset(||)C-CH_(3)overset(SeO_(2))rarrA,A will :

CH_(3)-overset(O)overset(||)C-CH_(3)overset(CH_(2)N_(2))rarr(X)overset(SeO_(2))rarrunderset(("major"))((Y))overset(m-CPBA)rarr(Z) Product (Z) is :

The molecules CH_(3)-overset(O)overset(||)C-CH_(2) -overset(O)overset(||)C-O-C_(2)H_(5) and CH_(3)-overset(OH)overset(|)C-OH-overset(O)overset(||)C-O-C_(2)H_(5) are

The IUPAC name for CH_(3)-overset(O)overset(||)(C)-CH_(2)-CH_(2)-overset(O)overset(||)(C)-OH is :

CH_(3)-overset(O)overset(||)C-CH_(3) " and " CH_(3)-overset(O)overset(||)(C)-H is differentiated by:

Compare the enol percent. (A ) CH_(3) CHO (B ) CH_(3) - overset(O) overset(||) (C ) - CH_(3) (C ) CH_(3) - overset( O ) overset(||) (C ) - CH_(2) - overset( O ) overset(||) (C )- CH_(3) (D ) CH_(3) - overset(O) overset(||) (C ) - CH_(2) - overset(O) overset(||) (C ) - H (E ) H- overset(O) overset(||) (C ) - CH_(2) - overset( O ) overset(||) (C ) -H ( F) - Ph- overset(O) overset(||) (C) - CH_(2) - overset(O ) overset(||) (C ) - CH_(3) (G ) Ph - overset(O) overset(||) (C ) -CH_(2)- overset(O )overset(||) (C ) - Ph

ALLEN-ALKENE, ALKANE & ALKYNE -EXERCISE-5[B]
  1. An organic compound C(3)H(6)O does not give a precipitate with 2,4-Din...

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  2. Under Wolff Kishner reduction conditions, the conversions which may be...

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  3. CH(3)-overset(O)overset(||)C-CH(3)+[O]overset(SeO(2))rarrP+Se+H(2)O ...

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  4. In the Cannizzaro reaction given below: 2Ph-CHO overset(overset(Θ)OH...

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  5. Which of the following will give yellow precipitate with I(2)//NaOH-

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  6. Among the given compounds, the most susceptible to nucleophilic attack...

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  7. In a Cannizaro reaction the intermediate that will be the best hydride...

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  8. CH(3)CHO+H(2)NHOrarrCH(3)-CH=N-OH The above reaction occurs at

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  9. Among the following compounds , which will react with acetone to give ...

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  10. The product (s) via - oxymercuration (HgSO(4)+H(2)SO(4)) of 1- butyne...

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  11. Which of the following will not undergo aldol condensation-

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  12. Which of the following will react with water?

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  13. The enol form of acetone after treatment with D(2)O gives:

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  14. Which of the following has the most acidic hydrogen ?

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  15. The appropriate reagent for the following transformation is

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  16. Assertion : Dimethyl sulphide is commonly used for the reduction of a...

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  17. A mixture of benzaldehyde and formaldehyde on heating with aqueous NaO...

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  18. Compound 'A' (molecular formula C(3)H(8)O) is treated with acidified p...

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  19. Any one of the product formed is :

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  20. The product of acid hydrolysis of P and Q can be distinguished by

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