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Compound (A) (C(8)H(8)O) on treatment wi...

Compound (A) `(C_(8)H_(8)O)` on treatment with `NH_(2)OH.HCl` gives (B) and (C ). (B) and (C ) rearrange to give (D) and E, respectively, on treatment with acid. (B), (C ), (D), and (E ) are all isomers of molecular formula `(C_(8)H_(9)NO)`. When (D) is boiled with alcoholic KOH, an oil (F) `(C_(6)H_(7)N)` separates out. (F) reacts rapidly with `CH_(3)COCl` to give back (D). On the other hand, (E ) on boiling with alkali followed by acidification gives a white solid (G) `(C_(7)H_(6)O_(2))`. Identify (A) to (G).

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ALLEN-ALKENE, ALKANE & ALKYNE -EXERCISE-5[B]
  1. Suggest appropriate structures for the missing compounds. (The number ...

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  2. Complete the following :

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  3. Compound (A) (C(8)H(8)O) on treatment with NH(2)OH.HCl gives (B) and (...

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  4. Carry out the following transformation in not more than three steps. ...

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  5. An organic compound (A) (C(6)H(10)O) on reaction with CH(3)MgBr follow...

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  6. An organic compound (A) reacts with H(2) to give (B) and (C) suC Cessi...

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  7. What'is X?

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  8. The smallest ketone and its next homologue are reacted with NH(2)OH to...

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  9. Cyclohexene on ozonolysis followed by reaction with zinc dust and wate...

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  10. Statement-I: Glucose gives a reddish-brown precipitate with Fehiling's...

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  11. In the following reaction sequence, products I, J, and L are formed. K...

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  12. In the following reaction sequence, products I, J, and L are formed. K...

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  13. In the following reaction sequence, products I, J, and L are formed. K...

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  14. A tertiary alcohol (H) upon acid-catalysed dehydration gives a product...

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  15. A tertiary alcohol (H) upon acid-catalysed dehydration gives a product...

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  16. A tertiary alcohol (H) upon acid-catalysed dehydration gives a product...

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  17. A carbonyl compound (P) which gives positive iodoform test, undergoes ...

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  18. A carbonyl compound (P) which gives positive iodoform test, undergoes ...

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  19. A carbonyl compound (P) which gives positive iodoform test, undergoes ...

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  20. An acyclic hydrocarbon P, having molecular fromula C(6)H(10) gave acet...

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