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Which of the following is not isostruct...

Which of the following is not isostructural with `SiCI_(4)` ?

A

`SCl_4`

B

`SO_4^(2-)`

C

`PO_4^(3-)`

D

`NH_4^(+)`

Text Solution

Verified by Experts

The correct Answer is:
A

`SCl_4` is not isostructural with `SiCl_4` because it shows square planar structure due to involvement of repulsion between lone pair and bond pair of electrons.
`SO_4^(2-)` shows tetrahedral structure due to `sp^3` hybridisation.
`PO_4^(3-)` shows tetrahedral structure due to `sp^3` hybridisation.
`NH_4^(+)` shows tetrahedral structure due to `sp^3` hybridisation.
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NEET PREVIOUS YEAR (YEARWISE + CHAPTERWISE)-CHEMICAL BONDING-EXERCISE
  1. Which of the following is not a correct statement ?

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  2. The electronegaivity difference between N and F is greater than that b...

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  3. Which of the following is not isostructural with SiCI(4) ?

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  4. The number of unpaired electrons in a parmamagnetic diatomic molecule ...

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  5. Which of the following species has a linear shape?

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  6. In which of the following molecules are all the bonds not equal ?

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  7. The correct sequence of increasing covalent character is represent by

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  8. Which of the following would have permanent dipple moment ?

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  9. Which molecule has trigonal planar geometry ?

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  10. In BrF(3) molecule, the lone pair occupies equatorial position minimiz...

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  11. H2O is dipolar, whereas BeF2 is not. It is because

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  12. In an octahedral structure , the pair of d orbitals involved in d^(2)...

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  13. In a regular octahedral molecule MX(6) the number of X - M - X bonds ...

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  14. Among the following the pair in which the two species are not isostruc...

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  15. Which of the following statement is not correct for sigma and pi- bond...

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  16. In NO3^- ion, the number of bond pair and lone pair of electrons no N-...

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  17. Which of the following has ppi-dpi bonding?

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  18. Which of the following is isoelectronic ?

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  19. The main axis of diatomic molecule is z. The orbitals px and py overla...

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  20. In X - H----Y , both X and Y are electronegative elements

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