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Why do Zr and Hf exhibits similar proper...

Why do Zr and Hf exhibits similar properties?
Why do transition metal show variable oxidation states.

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### Step-by-Step Text Solution: **1. Similar Properties of Zr and Hf:** - **Reason for Similar Properties:** Zirconium (Zr) and Hafnium (Hf) exhibit similar properties primarily due to the phenomenon known as **lanthanide contraction**. - **Explanation of Lanthanide Contraction:** - Lanthanide contraction refers to the gradual decrease in the size of the lanthanide series elements as the atomic number increases. This occurs because the f-electrons, which are being added to the f-orbitals, do not shield the nuclear charge effectively. - As a result, the effective nuclear charge felt by the outer electrons increases, leading to a decrease in atomic size. - **Impact on Zr and Hf:** ...
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