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Iodobenzene is prepared from aniline (C(...

Iodobenzene is prepared from aniline `(C_(6)H_(5)NH_(2))` in a two step process as shown here:
`C_(6)H_(5)NH_(2)+HNO_(2)+HCl to C_(6)H_(5)N_(2)^(+)Cl+2H_(2)O`
`C_(6)H_(5)N_(2)^(+)Cl^(-)+KI to C_(6)H_(5)I+N_(2)+KCl`
In an actual preparation, 9.30g of aniline was converted to 12.32g of iodobenzene. The percentage yield of iodobenzene is:

A

0.08

B

0.5

C

0.75

D

0.8

Text Solution

Verified by Experts

The correct Answer is:
D

`1"mole of "C_(6)H_(5)NH_(2)(123g)-=1"mole of "C_(6)H_(5)I(204g)`
`therefore "9.3g of aniline will give"=((204)/(123)xx9.3)"g iodobenzene"`
=15.24g iodobenzene
`"% yield"=("Actual amount of product")/("Calculated amount of product")xx100`
`=(12.32)/(15.424)xx100=80%`
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Iodobenzene (C_(6)H_(5)l) is prepared from aniline (C_(6)H_(5)NH_(2)) in a two step process as shown below C_(6)H_(5)NH_(2) + HNO_(2) + HCl rarr C_(6)H_(5)N_(2) .^(+)Cl^(-) + 2H_(2)O " "C_(6)H_(5)N_(2) .^(+)Cl^(-) + KI rarr C_(6)H_(5)I + N_(2) + KCl In an actual preparation 9.30 g of aniline was coverted to 16.32 g of iodobenzene. The percentage yield of iodobenzene is :

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