Home
Class 12
CHEMISTRY
Hydrocarbon (A) C(6)H(10), on treatment ...

Hydrocarbon (A) `C_(6)H_(10)`, on treatment with `H_(2)//Ni, H_(2)`/ Lindlar's catalylst and Na/liquid `NH_(3)` forms three different reduction products (B), ( C) and (D) respectiveluy. (A) does not form any salt with ammonial `AgNO_(3)` solution, but forms a salt (E) on heating with `NaNH_(2)` in an inert solvent. Compound (E) reacts with `CH_(3)I` to give (F). Compound (D) on oxidative ozonolysis gives n-butanoic acid along with other product.
Give structures of (A) to (F) with proper reasoning.

Text Solution

Verified by Experts

Promotional Banner

Topper's Solved these Questions

  • UNSATURATED HYDROCARBONS

    OP TANDON|Exercise BRAIN STORMING PROBLEMS|19 Videos

  • UNSATURATED HYDROCARBONS

    OP TANDON|Exercise OBJECTIVE QUESTIONS|194 Videos

  • UNSATURATED HYDROCARBONS

    OP TANDON|Exercise Match type|1 Videos

  • STOICHIOMETRY (CHEMICAL FORMULAE AND EQUATIONS )

    OP TANDON|Exercise SELF ASSESSMENT|11 Videos

Similar Questions

Explore conceptually related problems

Hydrocarbon (A) C_(6)H_(10) on treatment with H_(2)/Ni, H_(2)// Lindlar's catalyst or Na// liq. NH_(3) forms three different reduction products (B), (C), (D) respectively. (A) does not form any salt with ammonical AgNO_(3) solution, but (E) forms salt on heating with NaNH_(2) in an inert solvent. Compound (E) reacts with CH_(3)l to give (F). Compound (D) on oxidative ozonolysis gives n-butanoic acid along with other product. (F) on ozonolysis will produce -

An organic compound (E)(C_(5)H_(8)) , on hydrogenation gives a compound (F)(C_(5)H_(12)) . Compound (E) on ozonolysis gives formaldehyde and 2- ketopropanal. Deduce the structure of the compouns (E) .

An organic compound C_(4)H_(6) on reductive ozonolysis gives HCHO,CO_(2) and CH_(3)C=CH-CH=CH_(2) Find structure of compound.

An organic compound (A) gives opsitive Liebermann reaction and on treatment with CHCI_(3)//KOH followed by hydrolysis gives (B) and (C). Compound (B) gives colour with Schiff's reagent but not (C), which is steam volatile. (C ) on treatment with LiAIH_(4) gives (D), C_(7)H_(8)O_(2) , which on oxidation gives (E). Compound (E) reacts with (CH_(3)CO)_(2))O//CH_(3)COOH to give a pain reliever (F). Give the structures of (A) to (F) with proper reasoning.

The three compounds (A),(B), and (C) on hydrogenation with H_(2)+Pd give (D),(E) and (F) , respectively. Compounds (D),(E) and (F) are :

An organic compound (A) C_(5)H_(9) Br which readily decolourises bromine water and KMnO_(4) solution gives (B), C_(5)H_(11)Br on treatment with Sn//HCI . The reaction of (A) with NaNH_(2) produces (C) with evolution of ammonia (C) neither reacts with sodium nor forms any metal acetylide but reacts with Lindlar catalyst to give (D) and on reaction with Na//liq . NH_(3) produces (E) .Both the compounds (D) and (E) are isomeric. Give structures of (A) to (E) with proper reasoning.