Home
Class 12
CHEMISTRY
An unsaturated compound C(6)H(12) A) dec...

An unsaturated compound `C_(6)H_(12)` A) decolourless `Br_(2)`. Water and on oxidation by acidified `KMnO_(4)` gives optically active carboxylic acid `C_(4)H_(9)COOH` (B). Give the structure of (A) and (B).

Text Solution

Verified by Experts

Compound is unsaturated because it is decolouring `Br_(2)` water. On oxidation it gives a carboxylic acid with one carbon atom less than alkene, it shows that corresponds is terminal alkene. Thus, structure of terminal alkene with chiral carbon can be given as:
Promotional Banner

Topper's Solved these Questions

  • UNSATURATED HYDROCARBONS

    OP TANDON|Exercise OBJECTIVE QUESTIONS|194 Videos
  • UNSATURATED HYDROCARBONS

    OP TANDON|Exercise (LEVEL B) OBJECTIVE QUESTIONS|29 Videos
  • UNSATURATED HYDROCARBONS

    OP TANDON|Exercise PROBLEMS BASED ON STRUCTURE AND PROPERTIES|10 Videos
  • STOICHIOMETRY (CHEMICAL FORMULAE AND EQUATIONS )

    OP TANDON|Exercise SELF ASSESSMENT|11 Videos

Similar Questions

Explore conceptually related problems

A carboxylic acid C_(2)H_(4)O_(2) reacts with an alcohol in the presence of H_(2)SO_(4) to form a compound 'X'. The alcohol on oxidation with alkaline KMnO_(4) gives the same carboxylic acid, C_(2)H_(4)O_(2) . Write the name and structure of (i) Carboxylic acid, (ii) alcohol and (iii) the compound 'X'.

An organic compound (A) of molecular formula C_(5)H_(8) when treated with Na in liquid ammonia followed by reaction with s-Propyl iodide yeidls (B) C_(8)H_(12) (A) gives a ketone C_(5)H_(10)O (e) when treated with dil H_(2)SO_(4) and HgSO_(4) (B) on oxidation with alkaline KMnO_(4) gives two isomeric acids (D) and (E) C_(4)H_(8)O_(2) . Give structures of compounds (A) to (E) with proper reasoning .

The number of optically active compounds in the isomers of C_(4)H_(9)Br is

Compound (A)(C_(12)H_(16)) on oxidation with acideic KMnO_(4) solution gives acetone and . Identify compound (A) .

C(C_(6)H_(12)) , and optically active dydrocarbon which on catalytic hydrogenation gives an optically inactive compound, C_(6)H_(14) .