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Oxidation without clevage of sigma bond ...

Oxidation without clevage of sigma bond takes place in alkenes.

Presence of unsaturation in alkenes is detected by using Baeyer's reagent. Alkenes decolourise pink colour of Baeyer's reagent. In presence of Baeyer's reagent, 'syn' addition of -OH groups takes place on both carbons of double bond. The net reaction can be given as,
`R-CH=CH-R overset(KMnO_(4))underset(OH^(-))to R-overset(OH)overset(|)(CH)-overset(OH)overset(|)(CH)-R`
Ozonolysis of alkenes gives ozonide, which on further hydrolysis gives aldehyde and/ or ketone.

Product of ozonolysis gives information about:

A

configuration

B

conformation

C

both of these

D

none of these

Text Solution

Verified by Experts

The correct Answer is:
D
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Oxidation without clevage of sigma bond takes place in alkenes. Presence of unsaturation in alkenes is detected by using Baeyer's reagent. Alkenes decolourise pink colour of Baeyer's reagent. In presence of Baeyer's reagent, 'syn' addition of -OH groups takes place on both carbons of double bond. The net reaction can be given as, R-CH=CH-R overset(KMnO_(4))underset(OH^(-))to R-overset(OH)overset(|)(CH)-overset(OH)overset(|)(CH)-R Ozonolysis of alkenes gives ozonide, which on further hydrolysis gives aldehyde and/ or ketone. ortho Xylene on reductive ozonolysis will be:

Oxidation without clevage of sigma bond takes place in alkenes. Presence of unsaturation in alkenes is detected by using Baeyer's reagent. Alkenes decolourise pink colour of Baeyer's reagent. In presence of Baeyer's reagent, 'syn' addition of -OH groups takes place on both carbons of double bond. The net reaction can be given as, R-CH=CH-R overset(KMnO_(4))underset(OH^(-))to R-overset(OH)overset(|)(CH)-overset(OH)overset(|)(CH)-R Ozonolysis of alkenes gives ozonide, which on further hydrolysis gives aldehyde and/ or ketone. Which of the following will give only formaldehyde on ozonolysis?

Oxidation without clevage of sigma bond takes place in alkenes. Presence of unsaturation in alkenes is detected by using Baeyer's reagent. Alkenes decolourise pink colour of Baeyer's reagent. In presence of Baeyer's reagent, 'syn' addition of -OH groups takes place on both carbons of double bond. The net reaction can be given as, R-CH=CH-R overset(KMnO_(4))underset(OH^(-))to R-overset(OH)overset(|)(CH)-overset(OH)overset(|)(CH)-R Ozonolysis of alkenes gives ozonide, which on further hydrolysis gives aldehyde and/ or ketone. Which of these compounds give glyoxal only on ozonolysis?

Oxidation without clevage of sigma bond takes place in alkenes. Presence of unsaturation in alkenes is detected by using Baeyer's reagent. Alkenes decolourise pink colour of Baeyer's reagent. In presence of Baeyer's reagent, 'syn' addition of -OH groups takes place on both carbons of double bond. The net reaction can be given as, R-CH=CH-R overset(KMnO_(4))underset(OH^(-))to R-overset(OH)overset(|)(CH)-overset(OH)overset(|)(CH)-R Ozonolysis of alkenes gives ozonide, which on further hydrolysis gives aldehyde and/ or ketone. Answer the following questions: Liner polyenes on ozonolysis gives two moles of acetaldeyde and one mole of propanedial. Linear polyene will be:

Decolourisation of baeyer's reagent indicates the presence of

The number of meso form of the given compound (A) is CH3-overset(OH)overset(|)(CH)-overset(OH)overset(|)(CH)-overset(OH)overset(|)(CH)-CH_3

CH_(3)-underset(CH_(3))underset(|)(CH)-CH=CH-CH_(2)-overset(O)overset(||)(C)-OH

R-overset(O)overset(||)(C )-O-Hoverset(x)(rarr)R-CH_(2)-OH X can be

CH_3-overset(OH)overset(|)(CH)-overset(O)overset(||)(C )-CH_2 - CH_(3) will respond to

The IUPAC name of CH_(3)-underset(CH_3)underset(|)overset(OH)overset(|)"C"-CH_(2)-overset(OH)overset(|)"CH"-CH_(3) is

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