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Write the names of reagents and equations for the preparation of following ethers by Williamson's synthesis `:`
(i) 1-Methyoxypropane (ii) 2-Ethoxy-2-methylpropane
(iii) Ethoxybenzene

Text Solution

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`(i) underset("Sodium propoxide")(CH_(3)CH_(2)CH_(2)overset(-)(O)Na^(+))+underset("Bromomethane")(Br-CH_(3))overset("Heat")(rarr)underset("1-Methoxypropane")(Ch_(3)CH_(2)CH_(2)-O-CH_(3))+NaBr `
(ii) `underset("Sodium -2-methyl-2-propoxide")(CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-overset(-)(O)Na^(+))+underset("Bromoethane")(Br-C_(2)H_(5))overset("Heat")(rarr)underset("2-Ethoxy-2-methylpropane")(CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-OC_(2)H_(5))+NaBr`
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IUPAC Name|Preparation Of Ethers|Williamson Synthesis|Summary

OP TANDON-ALCOHOLS, PHENOLS AND ETHERS-ETHERS
  1. How would you bring the following conversions ? (i) Ethyl alcohol to...

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  2. Give the major product formed by heating the following ethers with con...

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  3. Write the names of reagents and equations for the preparation of follo...

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  4. Compound (A) C(4)H(10)O, is found to be soluble in sulphuric acid . (...

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  5. A neutral compound (A) having C,H and O, on refluxing with HI yields m...

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  6. (A) Ether behaves as bases in the presence of mineral acids. (R ) Du...

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  7. (A ) The boiling point of ethanol is much higher than that of diethyl ...

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  8. (A) Phenetole on clearvage with HI yields phenol and ethyl iodide (R...

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  9. Assertion: Anisole undergoes eletctrophilic substitution at o-and p-po...

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  10. (A) With HI, anisole forms iodobenzene and methyl alcohol. (R ) I^(-...

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  11. (A) tert-Butyl methyl ether on cleavage with HI at 373K gives tert-but...

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  12. (A) The C-O-C bond angle in ethers is higher than H-O-H bond angle in ...

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  13. (A) tert-Butyl alcohol on heating with conc. H(2)SO(4) at 413K gives 2...

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  14. (A) 1-Bromo-2,2-dimethyl propane on heating with ethanol gives 2-ethox...

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  15. Assertion. t-Butyl Methyl ether is not prepared by the reaction of t-b...

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  16. (A) Oxirane are cleaved under acidic and basic conditions. (R ) The ...

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  17. (A) Diphenyl ether is prepared by Ulmann reaction as shown below : ...

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  18. Match the following :

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  19. Match the following : (d) HOCH(2)CHOHCH(2)OH underset(("excess"))...

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  20. Match the following :

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