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In the reaction, C(6)H(5)NH(2)underset...

In the reaction,
`C_(6)H_(5)NH_(2)underset(0-5^(@)C)overset(NaNO_(2)+HCl)rarr(A)underset(KCN)overset(CuCN)rarr(B)overset(H^(+)//H_(2)O)rarr(C)`
the product `( C)` is

A

`C_(6)H_(5)CH_(2)NH_(2)`

B

`C_(6)H_(5)COOH`

C

`C_(6)H_(5)OH`

D

none of these

Text Solution

Verified by Experts

The correct Answer is:
B
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underset((0-5^(@)C))overset(NaNO_(2)//HCl)rarr A overset(CuCN)rarrB overset( H_(2)O // H^(+))rarrC What is product (B) .

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Identify 'C' in the following sequence : C_(6)H_(5)NH_(2) underset(273 K)overset(NaNO_(2) + HCl) rarr A overset(CuCN)rarr B overset(LiAIH_(4))rarr C

Identify Y in the reaction, C_(6)H_(5)NH_(2) underset(273K)overset(NaNO_(2)//HCl)to X underset(dil." "H_(2)SO_(4))overset(H_(2)O)toY

Identify X, Y and Z in the following reactions : (a) C_(6)H_(5)NH_(2) underset(HCl)overset(NaNO_(2))rarr X underset(HBr)overset(CuBr)to Y underset("623 K, pressure")to Z (b) C_(6)H_(6) overset(Cl_(2).FeCl_(3))to X overset(CuCN)to Y overset(dil.HCl)to Z (c) C_(6)H_(5)N_(2)^(+)Cl^(-) underset("warm")overset(KI)to X overset(Cu)to Y

OP TANDON-ORGANIC COMPOUNDS CONTAINING NITROGEN-Level A
  1. Aniline when treated acetyl chlroide in presence of alkali, the produc...

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  2. In the diazotisation of aryl amine, the use of nitrous acid is:

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  3. In the reaction, C(6)H(5)NH(2)underset(0-5^(@)C)overset(NaNO(2)+HCl)...

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  4. Benzene diazonium chloride on hydrolysis gives

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  5. Chlorobenzene can be prepared by reacting aniline with

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  6. The product of reaction between anilne and acetic andyide is:

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  7. Benzylamine is a stronger base than aniline because

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  8. Friedel-Crafts reaction is not given by:

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  9. When benzene diazonium chloride is treated with cuprous chloride in H...

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  10. The nitration (using nitration mixture) of aniline gives:

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  11. Examine the following two structures for the anilinium ion and choose ...

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  12. Which of the following would not react with benzene sulphonyl chloride...

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  13. Which of the following would not react with HNO(2)?

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  14. Which of the following is least basic?

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  15. The product of the above reactions is:

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  16. Dyes are formed when benzene diazonium salts are coupled with:

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  17. An aromatic amine (X) was treated with alcoholic potash and another co...

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  18. Aniline when acetylated, the product on nitration followed by alkaline...

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  19. Method by which Aniline can t be prepared is .

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  20. In the following compounds The order of basicity is

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