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Amino group, -NH(2) is ortho, para-direc...

Amino group, `-NH_(2)` is ortho, para-directing group in case of aromatic electrophilic substitution but nitration of aniline produce a good amount of m-nitroaniline. This is because

A

in nitration mixture, ortho-para-activity of -`NH_(2)` group is completely lost

B

`-NH_(2)"becomes" -NH_(3)^(+),"which is m-directing"`

C

`-NH_(2)"becomes" -NH^(+)SO_(4)^(-),"which is m-directing"`

D

`-NH_(2)"becomes" -NH^(-)NO_(2)^(+),"which is m-directing"`

Text Solution

Verified by Experts

The correct Answer is:
B
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OP TANDON-ORGANIC COMPOUNDS CONTAINING NITROGEN-Level A
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